Polymerization catalyst systems and processes therefor and...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Phosphorus or compound containing same

Reexamination Certificate

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C502S114000, C502S118000, C526S169000, C526S153000, C526S134000, C526S139000, C526S145000

Reexamination Certificate

active

10997727

ABSTRACT:
A copolymer of ethylene and a higher alpha olefin, preferably 1-hexene, can be produced using an activated chromium containing catalyst system and a cocatalyst selected from the group consisting of trialkylboron, trialkylsiloxyalutninum, and a combination of trialkylboron and thalkylaluminum compounds. The polymerization process must be carefully controlled to produce a copolymer resin having an exceptionally broad molecular weight distribution, extremely high PENT ESCR values, and a natural branch profile that impacts branching preferably into the high molecular weight portion of the polymer. The resulting copolymer resin is especially useful in high stiffness pipe applications.

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