Polymerization catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502104, 526114, C08F 464

Patent

active

045621705

ABSTRACT:
An olefin polymerization catalyst produced by treating a inert porous support material preferably a hydrated high surface area silica support having 1.00 to 1.50 hydroxyls per gram of silica with the reaction product of an organomagnesium compound and first a hafnium compound then a halogenator and tetravalent titanium compound, which when used as a cocatalyst with an organoaluminum compound produces polymers having broad molecular weight distribution.

REFERENCES:
patent: 3135809 (1964-06-01), Bosmajian
patent: 3734899 (1973-05-01), Fodor
patent: 3812089 (1974-05-01), Tashiro et al.
patent: 4226965 (1980-10-01), Grigoriev et al.
patent: 4471066 (1984-09-01), Sakurai et al.

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