Polymerizable diazonium salts, process for the preparation...

Organic compounds -- part of the class 532-570 series – Organic compounds – Diazo or diazonium

Reexamination Certificate

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C136S263000

Reexamination Certificate

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07812139

ABSTRACT:
Polymerizable diazonium salts having redox properties and absorption in the visible range, a process for preparing them and uses thereof are disclosed. The salts have the general formula:in-line-formulae description="In-line Formulae" end="lead"?[XX+LnDdEm(N2+)p][(B−)p+x]in-line-formulae description="In-line Formulae" end="tail"?in which:X is chosen from transition metals, preferably X is chosen from ruthenium (Ru), osmium (Os), iron (Fe), cobalt (Co) and iridium (Ir),x is an integer ranging from 1 to 5 inclusive,L is a ligand chosen from pyridine, bipyridine, terpyridine, phenanthroline and phenylpyridine groups, and mixtures thereof,n is an integer ranging from 1 to 5 inclusive,D is a saturated or unsaturated, C1-C5alkyl spacer compound,d=0 or 1,E is an aromatic or polyaromatic spacer compound that can contain one or more heteroatoms,m is an integer ranging from 0 to 5 inclusive,p is an integer, andB is a counterion.

REFERENCES:
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Isied, S. et al.,: “Rates of Substitution in Cis and Trans Ruthenium(II) Aquotetraamines”; Inorganic Chemistry; vol. 15, 1976; pp. 3070-3075; XP002424377.
Ware, D.C., Taube, H.: “Substitution-Induced N-N Coupling for Nitride Coordinated to Osmium(VI)”; Inorganic Chemistry; vol. 30, 1991; pp. 4605-4610; XP002424378.
Magnuson, R.H., Taube, H.: “Synthesis and Properties of Osmium(II) and Osmium(III) Ammine Complexes of Aromatic Nitrogen Heterocyles”; J Am. Chem. Soc.; 1975; pp. 5129-5136; XP002424379.

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