Polymeric peroxides derived from hydroxy-hydroperoxides and dihy

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525451, 526216, 5262305, 5262323, 528 49, 528 76, 528 85, 528272, 528301, 528370, 528372, 528263, 528264, 528265, 560158, 560198, 560202, C08L 7500

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050397540

ABSTRACT:
A polymeric peroxide comprising a dilvalent recurring unit having the formula: ##STR1## wherein the recurring unit of Formula I has a 10 hour half-life temperature of at least 80.degree. C. and optionally a divalent recurring unit having the formula: ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.5, X, X.sup.1, Y, Z, y and z are as defined in the Detailed Description of the Preferred Embodiments and the polymeric peroxide has a molecular weight of 1,000 to 200,000. The polymeric peroxides are derived from hydroxy-hydroperoxides of dihydroxy dialkyl peroxides. These polymeric peroxides can be used for preparing block copolymers and compatibilizing polymer blends and alloys.

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Polymer Handbook, 2nd Ed., John Wiley & Sons, New York, pp. I-1-I-13.
Kirk-Othmer Encyclopedia of Chemical Technology, 3rd Ed., "Urethane Polymers," (Henri Ulrich), pp. 576-608.
B. Hazer, "Polymerization of Vinyl Monomers by New Oligoperoxide: Oligo(Adipoyl-5-Peroxy-2,5-Dimethyl n-Hexyl Peroxide)", Journal of Polymer Science: Part A: Polymer Chemistry, vol. 25, pp. 3349-3354 (1987).

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