Polymeric peroxide, polymerization initiator and method for prod

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5262323, 526227, 526232, 526230, 526213, 568561, 568566, 560302, C07C40900, C07C40930, C07C40934, C07C40938

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active

052584658

ABSTRACT:
An ester type polymeric peroxide; has a peroxide group of the formula (I): ##STR1## a group of the formula (I') ##STR2## a group of the formula (II) ##STR3## wherein X stands for one member selected from the group consisting of --CH.sub.2 --CH.sub.2 --, --C.tbd.C-- and ##STR4## continuously bound such that I and I' occur randomly in alternation with II, having a (I):(I') molar ratio in the range of from 9:1 to 1:9 and the [(I)+(I')]:(II) molar ratio in the range of from 6:4 to 4:6, and having an average molecular weight in the range of from 1,000 to 20,000, a polymerization initiator for vinyl type monomer comprising said ester type polymeric peroxide and method for the production of a block copolymer of vinyl type monomer by said polymerization initiator.

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patent: 4954656 (1990-09-01), Suyama et al.
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patent: 5117047 (1992-05-01), Suyama et al.

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