Polymeric isocyanate-hydroxy terminated polybutadiene compositio

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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102103, 528 52, 528 53, 528 57, C08F 1824

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041872150

ABSTRACT:
A composition and method are disclosed in which a homopolymeric isocyanate such as a toluene diisocyanate polymer is formed IN SITU within a polyurethane composition containing a hydroxy-terminated organic compound, preferably a polybutadiene, an amount of self-polymerizable polyisocyanate in excess of the stoichiometric requirement, and a polymerization catalyst therefor. The composition can be fully cured on a surface and yet provides an excess of stable material, i.e. dormant isocyanate containing groups which are reactive on demand to strengthen interfaces with adjacent layers containing available hydroxyl groups, such as a layer of solid polyurethane-based propellant, without the need for intermediate reactive coatings.

REFERENCES:
patent: 3433158 (1969-03-01), Pierce
patent: 3507114 (1970-04-01), Webb
patent: 3636881 (1972-01-01), Godfrey

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