Polymeric carbonylation catalyst system

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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562521, 562522, C07C 5112, C07C 5308

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active

054668743

ABSTRACT:
A carbonylation catalyst useful for the carbonylation of methanol to acetic acid, acetic anhydride or both comprises a polymer support containing pendant pyrrolidone groups which support a rhodium species. Other polymeric supports capable of withstanding carbonylation temperatures of at least 150.degree. C. are disclosed for the carbonylation reaction in which rhodium levels in the reaction medium of greater than 500 ppm are contemplated.

REFERENCES:
patent: 3769329 (1973-10-01), Paulik et al.
patent: 3855307 (1974-12-01), Rony et al.
patent: 4066705 (1978-01-01), Hughes
patent: 4419490 (1983-12-01), Bayer et al.
patent: 4667053 (1987-05-01), Lin
patent: 5001259 (1991-03-01), Smith et al.
patent: 5026908 (1991-06-01), Smith et al.
patent: 5131943 (1992-07-01), Allison et al.
patent: 5155261 (1992-10-01), Marston et al.
patent: 5250489 (1993-10-01), Della Betta et al.
patent: 5258349 (1993-11-01), Della Betta et al.
patent: 5259754 (1993-11-01), Della Betta et al.
patent: 5334755 (1994-08-01), Yoneda et al.
"Acetic Acid by Low Pressure Carbonylation of Methanol with a Supported Rhodium Catalyst", by Wing S. Fong, Process Economics Program, Menlo Park, Calif., Feb. 1990, pp. 1-14.
"A Novel Copolymer-Bound Cis-Dicarbonylrhodium Complex for the Carbonylation of Methanol to Acetic Acid and Acetic Anhydride", Yuan Guoqing et al, Chinese Journal of Polymer Science, vol. 7, No. 3, 1989, pp. 219-224.
"Kinetic Study of Carbonylation of Methanol to Acetic Acid and Acetic Anhydride Over a Novel Copolymer-Bound CIS-Dicarbonylrhodium Complex", Chen Yuying et al, Chinese Journal of Polymer Science, vol. 7, No. 3, 1989, pp. 225-231.
"Design and Synthesis of a Solid Bifunctional Polymer Catalyst for Methanol Carbonylation", K. M. Webber et al, Journal of Molecular Catalysis, 3 (1977/78), pp. 1-9.
"Ionic Attachment as a Feasible Approach to Heterogenizing Anionic Solution Catalysts. Carbonylation of Methanol", R. S. Drago et al, Inorganic Chemistry, American Chemical Society, vol. 20, No. 3, Mar. 1981, pp. 641-644.
"Methanol Carbonylation Catalyzed by a Polymer-Bound Rhodium (I) Complex", M. S. Jarrell et al, Journal of Catalysis, 40, 1975, pp. 255-267.
"Methanol Carbonylation Catalyzed by Polymer-Supported Rhodium Complexes", Applied Catalysis, 35, (1987), pp. 279-288.
CA112 (12): 1011116d (1989).
CA112 (11): 98064c (1989).
CA109 (2): 839v (1989).
CA91 (14): 112972d (1979).
CA89 (11): 90020w (1978).
CA117 (6): 51254c (1992).
CA114 (25): 246784w (1989).
CA114 (25): 246530k (1989).
CA114 (12): 104708a (1989).
CA112 (26: 237139w (1989).
CA109 (9): 72943b (1987).
CA108 (18): 152558z (1986).
CA107 (25): 236050v (1987).
CA106 (23): 195856w (1985).
CA101 (23): 21057s (1982).
CA99 (2): 6232t (1981).
CA98 (15): 125509c (1983).
CA97 (4): 25529v (1980).
CA95 (16): 139381e (1981).
CA91 (15): 123409b (1977).
CA90 (7): 54480h (1977).
CA88 (2): 8078u (1977).
CA84 (15) 104661s (1975).

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