Stock material or miscellaneous articles – Pile or nap type surface or component – Composition of pile or adhesive
Reexamination Certificate
1999-02-16
2001-09-18
Juska, Cheryl (Department: 1771)
Stock material or miscellaneous articles
Pile or nap type surface or component
Composition of pile or adhesive
C428S095000, C428S096000, C428S354000
Reexamination Certificate
active
06291048
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a polymeric based carpet.
BACKGROUND OF THE INVENTION
It is desired in the textile industry to create products that are 100 percent recyclable with minimum difficulty. Today's commercially provided carpet products are predominantly manufactured using a latex based binder to adhere the backing scrim to the carpet fibers. The purpose of the scrim and latex are to bind the carpet fibers and prevent the fibers from becoming unwoven or loose. The latex is undesirable from a recycling point of view. In order to reclaim the carpet fibers and scrim, which are normally polypropylene, polyester, or polyamide based, the latex has to be separated from the total composite.
A method of making and recycling carpet of all recyclable material has been disclosed. The disclosed carpet includes a primary backing having tufts of synthetic carpet fibers protruding from a top surface and, optionally, a secondary backing, with an extruded sheet of an isotactic polyolefin polymer between and integrally fused to a bottom surface of the primary backing and an upper surface of the secondary backing. The isotactic polyolefin polymers shown to be effective to fuse the carpet fibers and the secondary backing in the disclosure are isotactic polypropylene and extruded blends of polypropylene with polyethylene, polybutylene and thermoplastic elastomers. The previous disclosures teach that polyethylene copolymers alone are a poor choice for such a fusion material. Furthermore, it has been disclosed that if anything other than polypropylene is used for the face fiber, extruded sheet and secondary back, that the bonding of the materials must be physically separated before recycling can take place.
In contrast, in the present invention, the use of ethylene methyl acrylate copolymers as such a fusion material replacement for latex conventionally used to bind carpet fibers to backing material not only eliminates the need for a separation recovery process but also enhances the total products' performance when recycled. Furthermore, such a copolymer has advantages over polypropylene and the various polypropylene blends previously disclosed.
SUMMARY OF THE INVENTION
The present invention relates to a carpet composition, recyclable without a separation step, having from 50 to 100 percent polymeric material comprising:
a) a tufted primary backing having a primary backing and tufts of carpet fibers penetrating a bottom surface of the primary backing and protruding from a top surface of the primary backing;
b) a secondary backing material; and
c) an extruded adhesive material or a coextrusion of two or more extruded adhesive materials binding an upper surface of the secondary backing material to the bottom surface of the primary backing;
in which the carpet fibers, primary backing material and secondary backing material are selected from the group consisting of polypropylene, polyester, acrylics, polyethylene, polyamide, nylon, wool, cotton, rayon and combinations thereof;
and in which the adhesive material comprises an amorphous polyethylene copolymer selected from the group consisting of ethylene methyl acrylate, ethylene normal butyl acrylate, and blends of two or more polyethylene copolymers.
In a preferred embodiment, the extruded adhesive material of the above described carpet composition comprises a middle layer of polyethylene sandwiched between two outer layers selected from the group consisting of ethylene methyl acrylate and ethylene normal butyl acrylate.
In a more preferred embodiment, the middle polyethylene layer of the above described extruded adhesive material is from 10 to 90 weight percent of the extruded adhesive material and each of the two outer layers is from 5 to 45 weight percent of the extruded adhesive material.
In another preferred embodiment, the adhesive material of the above described carpet composition further comprises maleic anhydride.
In yet another preferred embodiment, the adhesive material of the above described carpet composition is a coextruded blend of ethylene methyl acrylate copolymers and polymers selected from the group consisting of low density polyethylenes, linear low density polyethylenes, high density polyethylenes, ultra low density polyethylene having a density less than 0.915 density, ethylene-propylene copolymers, elastomers, rubber, EPDM (ethylene propylene diene monomer) rubber, styrenic copolymers of butadiene, styrenic copolymers of acrylonitrile, styrenic copolymers of ethylene, metallocene based polyethylenes, polypropylene, polyester, ethylene acrylic acid copolymers, ethylene methyl acrylic acid copolymers, butyl acrylate copolymers, ethylene vinyl acetate copolymers, ionomers, polyamides, and maleic anhydrides.
In still another preferred embodiment, the adhesive material of the above described carpet composition has a thickness of from 0.001 inches to 0.050 inches.
In yet another preferred embodiment, the adhesive material of the above described carpet composition further comprises additives selected from the group consisting of flame retardants, odor reduction additives, scent enhancing additives and ultra-violet light protection additives.
In still another preferred embodiment, the adhesive material of the above described carpet composition further comprises fillers selected from the group consisting of talc, calcium carbonate and other inorganic fillers.
The present invention also relates to a method of making a carpet, the carpet comprising a tufted primary backing with a primary backing and tufts of carpet fibers penetrating a bottom surface of the primary backing and protruding from a top surface of the primary backing; a secondary backing material; and an adhesive material binding an upper surface of the secondary backing material to the bottom surface of the tufted primary backing; the carpet fibers, primary backing material and secondary backing material being selected from the group consisting of polypropylene, polyester, acrylics, polyethylene, polyamide, nylon, wool, cotton, rayon and combinations thereof and the adhesive material comprising an amorphous polyethylene copolymer selected from the group consisting of ethylene methyl acrylate and ethylene normal butyl acrylate; the method comprising the steps of:
a) extruding a heated sheet of the adhesive material; and
b) continuously fusing together in a two roll nip the upper surface of the secondary backing and the bottom surface of the tufted primary backing with the heated sheet.
In a preferred embodiment of the above described method, the two roll nip comprises a hard roll and a soft roll.
In a more preferred embodiment of the above described method, the soft roll has a diameter of from 4 to 20 inches and a hardness of from 5 to 100 shore D.
In another more preferred embodiment of the above described method, the soft roll is comprised of rubber.
In still another more preferred method, the hard roll is a cooled metal chill roll capable of maintaining a temperature below 120° F.
In yet another more preferred method, the two roll nip has pressure between 20 and 200 pounds per linear inch.
The present invention also relates to a method of using at least one of ethylene methyl acrylate copolymer and ethylene normal butyl acrylate copolymer to manufacture a carpet, the carpet comprising a tufted primary backing with a primary backing and tufts of carpet fibers penetrating a bottom surface of the primary backing and protruding from a top surface of the primary backing; a secondary backing material; and an adhesive material binding an upper surface of the secondary backing material to the bottom surface of the tufted primary backing; the carpet fibers, primary backing material and secondary backing material being selected from the group consisting of polypropylene, polyester, acrylics, polyethylene, polyamide, nylon, wool, cotton, rayon and combinations thereof and the adhesive material comprising an amorphous polyethylene copolymer selected from the group consisting of ethylene methyl acrylate and ethylene normal butyl acrylate; the meth
Jerdee Gary D.
Kolm Roger
Medlock Eugene D.
Rodgers Brad D.
Eastman Chemical Company
Gwinnell Harry
Juska Cheryl
Wood Jonathan
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