Polymer surfaces for subsequent plating thereon and improved met

Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...

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428412, 428901, 428675, B32B 1508, B32B 1520

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active

051321912

ABSTRACT:
Method of modifying an aromatic polymer surface to improve adhesion of a metal layer thereon and to the articles produced therefrom. Polymer molecules disposed on the surface of the aromatic polymer such as polycarbonate, are nitrated by a contact with a nitrating solution such as a mixture of nitric and sulfuric acid and then ammonolytically cleaved by a contact with an ammonolytic solution such as ammonium hydroxide. The ammonolyzed surface is thus chemically modified to become hydrophilic. The chemically modified surface is electrolessly plated with a primary metal layer. A secondary metal layer is then electrolessly or electrolytically applied on top of the primary metal layer until a metal layer of a desired thickness is attained.
The present invention further discloses articles such as an EMI shielded enclosure or a printed circuit board having metal layers as an EMI shield or a conductive metal trace pattern respectively.

REFERENCES:
patent: 4775557 (1988-10-01), Bastenbeck et al.
patent: 4832799 (1989-05-01), Knudsen et al.
patent: 4941940 (1990-07-01), Patel et al.
patent: 4959121 (1990-09-01), Dumas et al.
Crivello, J., Nitrations and Oxidations with Inorganic Nitrate Salts in Trifluoroacetic Anhydride, 1981, pp. 3056-3060, J. Org. Chem., 46.
Rantell, A., The Influence of Surface Chemistry on the Adhesion of Copper Deposited on Plastic Substrates, 1969, pp. 197-202, Transactions of the Institute of Metal Finishing, vol. 47.

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