Polymer-supported arylbis(perfluoroalkylsulfonyl)-methane

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C525S333300, C525S333400, C525S333500, C525S343000

Reexamination Certificate

active

07026409

ABSTRACT:
The present invention provides a solid acid catalyst that is excellent from the point of toxicity, environment and others, wherein reaction can be progressed effectively with Bronsted acid or Lewis acid catalyst. For example, the benzoylation reaction of alcohol can also be progressed easily, and further, the catalyst can be recovered and recycled easily. The para position of arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [1] (wherein R1shows a substituted or unsubstituted aryl group, Rf1and Rf2are independent to each other and show a perfluoroalkyl group), a pentafluorophenylbis(perfluoroalkylsulfonyl)methane, for example, is supported on a polystyrene resin, and a polystyrene-supported arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [3] (wherein R3shows a substituted or unsubstituted arylene group, Rf1and Rf2are the same as described above) is obtained.

REFERENCES:
patent: 4049861 (1977-09-01), Nozari
patent: 4069368 (1978-01-01), Deyak et al.
patent: 4115295 (1978-09-01), Robins et al.
patent: 4337107 (1982-06-01), Eshleman et al.
patent: 4431845 (1984-02-01), Young et al.
patent: 4830847 (1989-05-01), Benedict et al.
patent: 5071737 (1991-12-01), Kita et al.
patent: 5932511 (1999-08-01), Harmer et al.
patent: 2004/0030192 (2004-02-01), Ishihara et al.
patent: 2005/0070741 (2005-03-01), Ishihara et al.
patent: 0 386 930 (1990-09-01), None
patent: 0 985 662 (2000-03-01), None
patent: 1 375 532 (2004-01-01), None
patent: 2 285 442 (1995-07-01), None
patent: 03-254697 (1991-11-01), None
patent: 07 246338 (1995-09-01), None
patent: WO 00/44495 (2000-08-01), None
English translation of the International Preliminary Examination Report (Form PCT/IPEA/409), and Notification of Transmittal (Form PCT/IB/338); mailed Dec. 5, 2003, from the International Bureau.
Patent Abstracts of Japan, English abstract of JP 07 246338A, Sep. 26, 1995.
Patent Abstracts of Japan, English abstract of JP 03 254697, Nov. 1991.
Nagayama et al, “A Novel Polymer-Supported Scandium Catalyst Which Shows High Activity in Water,” Angewandte Chemie International Edition, vol. 39, No. 3, Feb. 1, 2000, pp. 567-569.
Ishihara et al, “Polystyrene-bound Tetrafluorophenylbis(triflyl)methane As An Organic-Solvent-Swellable And Strong Bronsted Acid Catalyst,” Angewandte Chemie International Edition, vol. 40, No. 21, Nov. 5, 2001, pp. 4077-4079.
Ishihara et al, “Polystyrene-bound Tetrafluorophenylbis(triflyl)methane As An Organic-Solvent-Swellable And Strong Bronsted Acid Catalyst,” Angewandte Chemie, vol. 113, No. 21, Nov. 5, 2001, pp. 4201-4203.
Ishihara et al, “Pyrolysis of benzenediazonium bis(trifluoromethanesulfonyl)methide” Journal of Fluorine Chemistry, vol. 106, pp. 139-141, 2000.
Zhu, Shizheng, “Synthesis and Reactions of Phenyliodonium Bis(perfluoroalkanesulfonyl) Methides,” Heteroatom Chemistry, 1994, vol . 5, No. 1, pp. 9-18.
Zhu, Shizheng, “A new synthetic route to aryl bis(perfluoroalkanesulfonyl)methanes: structures of tolyldiazonium bis(trifluoromethanesulfonyl)methide and 4-nitrophenyl-hydrazono bis(trifluoromethanesulfonyl)methane,” J. Fluorine Chem., 1993, vol. 64, pp. 47-60.
Liston, David J. et al., “Observations on Silver Salt Metathesis Reactions with Very Weakly Coordinating Anions,” J. Am. Chem. Soc., 1989, vol. 111, pp. 6643-6648.
European Patent Office, Supplementary European Search Report for EP 02 70 2913, published Apr. 27, 2005.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Polymer-supported arylbis(perfluoroalkylsulfonyl)-methane does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Polymer-supported arylbis(perfluoroalkylsulfonyl)-methane, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Polymer-supported arylbis(perfluoroalkylsulfonyl)-methane will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3552533

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.