Polymer shell encapsulated gas as a cement expansion additive

Compositions: coating or plastic – Coating or plastic compositions – Inorganic settable ingredient containing

Reexamination Certificate

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C106S677000, C106S713000, C106S724000, C521S056000, C166S387000, C166S292000

Reexamination Certificate

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07494544

ABSTRACT:
Cement compositions containing an expandable material are disclosed. The compositions are suitable for use in oil and gas wells. An example of such an expandable material is a polymer encapsulated chemical that expands upon heating. Examples of cement compositions containing polymer encapsulated isobutane or isopentane are disclosed. The use of cement compositions containing an expandable material can reduce the formation of micro-annulus or other deleterious physical properties in the set cement.

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Website printout “The Product;” www.expancel.com; printed Apr. 21, 2003.
Website printout Boud Minerals & Polymers; Supplying Minerals and polymers to industry; printed Nov. 21, 2002; www.boud.com.
“Real-Time Cement Expansion/Shrinkage Testing Under Downhole Conditions for Enhanced Annular Isolation;” Virgilio C. Goboncan, SPE, Robert L. Dillenbeck, SPE, BJ Services; SPE/IADC; Feb. 2003.
“Chemical Resistance of Expancel; Unexpanded Microspheres;” Technical Bulletin No. 7; Oct. 1, 2001.

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