Polymer precursor for silicon carbide/aluminum nitride ceramics

Compositions: ceramic – Ceramic compositions – Carbide or oxycarbide containing

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501 88, 501 89, 501 93, 522148, 522172, C04B 3552

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active

055433693

ABSTRACT:
A block copolymer is prepared by reacting an aluminum-nitrogen polymer and a silazane polymer at a temperature not greater than 400.degree. C. Block copolymers containing alkenyl or alkynyl groups can be crosslinked by supplying energy to generate free radicals. An AlN/SiC-containing ceramic is formed by pyrolyzing the crosslinked block copolymer in a nonoxidizing atmosphere.

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Interrante et al., "Organometallic Precursors to AlN: Synthesis and Crystal Structures of [(CH.sub.3).sub.2 AlNH.sub.2 ].sub.3 and the Planar Species [(t-C.sub.4 H.sub.9).sub.2 AlNH.sub.2 ]).sub.3 ", Inorg. Chem., 28, 252-257, 1989.
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Janik et al., "Formation and Molecular Structure of the Novel Six-Coordinate Aminoalane Complex {[(CH.sub.3).sub.3).sub.3 Si].sub.2 Al(NH.sub.2).sub.2 }.sub.3 Al", Inorg. Chem., 27, 4335-4338, 1988.
Schmidt et al., "Novel Polymeric Precursors to Si-C-Al-O-N Ceramic Composites", presented at the Second International Ceramic Science and Technology Congress, Nov. 12-15, 1990, Orlando Fl.
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