Polymer electrolyte and polymer lithium battery

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

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Details

C429S317000, C429S320000, C429S322000

Reexamination Certificate

active

06924067

ABSTRACT:
A polymer electrolyte includes a substrate polymer, a branched polymer, and a lithium salt. The branched polymer has a main chain whose repeating unit is composed of an oligoethylene oxide chain and a connector molecule bonded to the oligoethylene oxide chain. The branched polymer can be a hyperbranched polymer. The polymer electrolyte can further include a composite oxide and/or a boroxine compound. The polymer electrolyte is good in terms of the ionic conductivity, and exhibits a high ionic conductivity especially at low temperatures. When the polymer electrolyte is used to make polymer lithium batteries, the resulting polymer lithium batteries shows improved charge-discharge cycle characteristics. In particular, it is possible to operate the polymer lithium batteries at low temperatures.

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Polymer electrolytes based on hyperbranched polymers. Journal of Power Sourdes (2001, 97-98, 637-640. Itoh et al.
Blend-based polymer electrolytes of poly(ethylene oxide) and hyperbranched poly[bis(triethylene glycol) benzoate] with terminal acetyl groups. Solid State Ionics (2000), 134(3,4), 281-289. Wen et al.
Characterization of composite electrolytes based on hyperbranched polymer. Journal of Power Sources (2000), 09(1), 20-26.Wen et al.
Ionic conductivity of the hyperbranched polymer-lithium metal salt systems. Journal of Power Sources. (1999), 81-82, 824-829 Itoh et al.
Thermal, electrochemical, and spectroscopic characterizations of hyperbranched polymer electrolyte.Journal of the Electrochemical Society (1999), 146(6), 2209-2215. Wang et al.
Effect of branching in base polymer on ionnic conductivity in hyperbranched polymer electrolyte. Solid State Ionics. (2002), 150(3,4), 337-345. Itoh et al.
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