Polymer compositions comprising electroactive amphiphilic organi

Details Polymer compositions comprising electroactive amphiphilic organi Polymer compositions comprising electroactive amphiphilic organi

1997-02-21

1998-07-21

Lieberman, Paul

Compositions

Electrically conductive or emissive compositions

549 35, 562899, H01B 106, H01B 112, H01B 120

Patent

active

057836434

ABSTRACT:
Polymeric compositions well suited for conversion into electroconductive shaped articles, e.g., films, comprise at least one convertible polymer (Pm) and at least one amphiphilic organic compound (B) which comprises a charge transfer complex or a radical ion salt having the formula (I): D.sub.d A.sub.a Z.sub.z, in which D is an electron donor; A is an electron acceptor; Z is a doping agent which itself can be a non-amphiphilic electron donor or electron acceptor, with the proviso that at least one of D and A is amphiphilic and contains at least one saturated or unsaturated hydrocarbon substituent having at least 10 carbon atoms; d is a number equal to or greater than 0; a is a number equal to or greater than 0; and z is a number equal to or greater than 0, with the further proviso that at least one of the symbols d and a is a number greater than 0.

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Vandevyver et al, "Behavior of Bis(Alkylthio)Tetrafulvalene Deriv. of Lanomuir-Blodgett Films Upon Iodine Exposure", J. Phys. Chem. 95(1), pp. 246-251, 1991.
IBM Technical Bulletin, vol. 20, No. 7, Dec. 1977, N. Y. pp. 2865-2867.
Polymer Journal, vol. 24, No. 3, Mar. 1992, Tokyo, pp. 273-279.
Chemical Abstacts, vol. 104, 1986, Columbis, Ohio, abstract No. 225469a, Inasawa, Shintaro "Conductive Polymers", p. 18, col. 1; & JP A 61 002 703 (Showa Denko K.K.) Jan. 1986.

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