Polyisocyanate mixtures which are liquid at greater than 5.degre

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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528 65, 25218221, 25218222, 560 25, C08G 1810

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active

056102607

ABSTRACT:
The present invention relates to polyisocyanate mixtures which are reaction products of 4,4'-diphenylmethane diisocyanate as the isocyanate component, are liquid at greater than 5.degree. C. and have an NCO content of 14.5 to 24% by weight and an allophanate group content (calculated as C.sub.2 HN.sub.2 O.sub.3, molecular weight = 101) of 7.7 to 14.5% by weight; a process for the production of these polyisocyanate mixtures by reacting 4,4'-diphenylmethane diisocyanate as the exclusive isocyanate component with one or more monohydric alcohols having 4 to 16 carbon atoms at an NCO/OH equivalent ratio of 5:1 to 8.5:1 and at a temperature of up to 160.degree. C. to form urethane groups and during or subsequent to urethane formation, converting the urethane groups to allophanate groups in the presence of a catalyst which promotes allophanate formation; and the use of these polyisocyanate mixtures as the polyisocyanate component in two-component polyurethane coating compositions.

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patent: 4088665 (1978-05-01), Findeisen et al.
patent: 4154752 (1979-05-01), Sundermann et al.
patent: 4738991 (1988-04-01), Narayan
patent: 4883909 (1989-11-01), Slack
patent: 5319053 (1994-06-01), Slack et al.
patent: 5319054 (1994-06-01), Slack et al.

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