Polyimides based on 4,4'-bis (4-aminophenoxy)-2,2'or 2,2', 6,6'-

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528125, 528128, 528170, 528172, 528173, 528174, 528175, 528179, 528183, 528185, 528188, 528220, 528229, 528350, C08G 7310

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active

059395214

ABSTRACT:
This invention relates the novel diamines, the polyimide oligomers and the polyimides derived therefrom and to the method of preparing the diamines, oligomers and the polyimides. The thermoplastic polyimides derived from the aromatic diamines of this invention are characterized as having a high glass transition temperature, good mechanical properties and improved processability in the manufacture of adhesives, electronic and composite materials for use in the automotive and aerospace industry. The distinction of the novel aromatic diamines of this invention is the 2,2',6,6'-substituted biphenyl radicals which exhibit noncoplanar conformation that enhances the solubility of the diamine as well as the processability of the polyimides, while retaining a realatively high glass transition temperature and improved mechanical properties at useful temperature ranges.

REFERENCES:
patent: 5091505 (1992-02-01), Serafini et al.
patent: 5268487 (1993-12-01), Yang et al.
patent: 5322924 (1994-06-01), Chuang et al.
patent: 5344986 (1994-09-01), Oren et al.

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