Polyimide AMD process for producing the same

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528125, 528128, 528170, 528171, 528172, 528173, 528176, 528183, 528185, 528188, 528220, 528229, 528310, 528322, 528350, C08G 7310, C08G 6926

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056962355

ABSTRACT:
Novel polyimides which are soluble in various organic solvents and excellent in thermal resistance, processability are disclosed. The polyimides comprise repeating units represented by the following formula (1) and/or (2) and having a number average molecular weight of 4,000-200,000. ##STR1## wherein Ar is a divalent group represented by the following formula (2) or (3): ##STR2## wherein Y is --O--, --CO--, --S--, --SO.sub.2 -- or --C(CH.sub.3).sub.2 --, ##STR3## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each a C.sub.1-4 alkyl group or a C.sub.1-4 alkoxy group, Ra is a divalent group having 2-6 benzene rings, X.sup.1 represents NH, NR (wherein R is a C.sub.1-4 alkyl group or a C.sub.1-4 alkoxy group) or S, Rb is C.sub.2-20 alkylene group, ether group or dimethylsiloxane group, and X.sub.2 represents NH, NR (wherein R is a C.sub.1-4 alkyl group or a C.sub.1-4 alkoxy group), ##STR4##

REFERENCES:
patent: 3741942 (1973-06-01), Crivello
patent: 5093459 (1992-03-01), Peter et al.
patent: 5106937 (1992-04-01), Yamaya et al.
patent: 5194567 (1993-03-01), Lewis
patent: 5457154 (1995-10-01), Ohta et al.
Organic Synthetic Chemistry, vol.43, No. 10 by Yoshio Imai pp. 932-940, (with its excerpt Japanese translation, Synthesis of Condensation Polymers by Michael-Tyoe addition Reaction.)(2-12-1).

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