Polyhaloaromatic ruthenium complexes and reactions thereof

Details Polyhaloaromatic ruthenium complexes and reactions thereof Polyhaloaromatic ruthenium complexes and reactions thereof

1993-11-30

1995-01-31

Dees, Jose G.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556136, C07F 1500, C07F 1702

Patent

active

053860446

ABSTRACT:
Novel ruthenium pi-arene complexes in which the arene ring has 3 or more halogen atoms bound to it are disclosed. These compounds are reacted with phenoxides and thiophenoxides to form ruthenium pi-arene complexes of polyfunctional aromatic ethers and thioethers which are useful as monomers and crosslinking agents.

REFERENCES:
Moriarity, R. M., et al., J. Organometal. Chem., 350, 157-190, 1988.
Gill, T. P., et al., Organometallics, 1, 485-488, 1982.
Wilkinson, G., et al., (Ed.), Comprehensive Organometallic Chemistry, 3, Pergamon Press, Oxford, 1001, 1982.
Wright, M. E., Organometallics, 8, 407-411, 1989.
Percec, V., et al., J. Polym. Sci. A, 31, 923-932, 1993.
Astruc, Tet., Tet. Reports No. 157, 39, 4037-4038, 1983.

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