Polyglycidamides

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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544200, 544204, 544208, 544256, 544209, 548304, C07D25100

Patent

active

048618810

ABSTRACT:
The polyglycidamides are epoxy derivatives of cyclic ureas such as glycouril and aminotriazines such as melamine and guanamines. They are prepared from cyclic ureas and aminotriazines by methylolating with formaldehyde, etherifying with an alcohol, transetheramidizing with acrylamide and epoxidizing with hydrogen peroxide. They are used with polyamines and other epoxy reactive oligomers to provide crosslinkable coating systems which possess solvent, chemical and water resistance and UV stability.

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Payne et al., Reactions of Hydrogen Peroxide VI, Alkaline Expoxidation of Acrylonitrile, J. of Org. Chem., vol. 26, pp. 651-659, Mar. 1961.

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