Polyfluorene method

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From hydrocarbon reactant

Reexamination Certificate

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C528S397000, C528S398000, C528S485000, C528S488000, C528S492000

Reexamination Certificate

active

07947801

ABSTRACT:
A method of synthesizing a poly(9,9-disubstituted-fluorene) includes reacting a 9,9-disubstituted-fluorene with an alkyl lithium in the presence of a catalytic amount of a nickel amine complex. The 9,9-disubstituted-fluorene includes solubility-enhancing substituents in the 9-position and leaving groups in the 2-position and the 7-position. The product poly(9,9-disubstituted-fluorene)s are fluorescent conjugated polymers that are useful as, for example, blue light-emitting materials.

REFERENCES:
patent: 6602974 (2003-08-01), McCullough et al.
Heeger, A. J. Angewandte Chemie, International Edition 2001, 40, 2591-2611.
Scherf, U.; List, E. J. W. Advanced Materials (Weinheim, Germany) 2002, 14, 477-487.
Schulter, A. D. Journal of Polymer Science, Part A: Polymer Chemistry 2001, 39, 1533-1556.
Marsitzky et al., Journal of the American Chemical Society 2001, 123, 6965-6972.
Yamamoto, T. Progress in Polymer Science 1992, 17, 1153-1205.
Yamamoto, T. et al., Macromolecules 1992, 25, 1214-1223.
Bunz, U. H. F. Chemical Reviews (Washington, D. C.) 2000, 100, 1605-1644.
Loewe, R. S. et al., Macromolecules 2001, 34, 4324-4333.
Loewe, R. S. et al., Advanced Materials (Weinheim, Germany) 1999, 11, 250-253.
Kim, Y. et al., Journal of Polymer Science, Part A.: Polymer Chemistry 2005, 44, 172-182.
Cao, J. et al., Synthetic Metals 2005, 152, 237-240.
Zhou, G. et al., Macromolecules 2005, 38, 5416-5424.
Grisorio, R. et al., Macromolecular Chemistry and Physics 2005, 206, 448-455.
Lee, J. et al., Macromolecules 2004, 37, 8523-8529.
Tu, G. et al., Applied Physics Letters 2004, 85, 2172-2174.
Zhou, X.-H.; Yan, J.-C.; Pei, J. Macromolecules 2004, 37, 7078-7080.
Bozano, L. D. et al., Journal of Applied Physics 2003, 94, 3061-3068.
Cho, H.-J. et al., Macromolecules 2003, 36, 6704-6710.
Asawapirom, U.; Scherf, U. Macromolecular Rapid Communications 2001, 22, 746-749.
Lee, J.-I.; Klaerner, G.; Miller, R. D. Chemistry of Materials 1999, 11, 1083-1088.
Klaerner, G.; Miller, R. D. Macromolecules 1998, 31, 2007-2009.
Pei, Q.; Yang, Y. Journal of the American Chemical Society 1996, 118, 7416-7417.
Carter, K. R. Macromolecules 2002, 35, 6757-6759.
Van Tamelen, et al., Journal of the American Chemical Society 1965, 87, 4964-4965.
Van Tamelen, et al., Journal of the American Chemical Society 1971, 93, 6141-6144.
Pasynkiewicz, S.; Lehmkuhl, H. Journal of Organometallic Chemistry 1985, 289, 189-200.
Lehmkuhl, H.; Pasynkiewicz, S.; Benn, R.; Rufinska, A. Journal of Organometallic Chemistry 1982, 240, C27-C29.
Pietrzykowski, A.; Pasynkiewicz, S. Journal of Organometallic Chemistry 1992, 440, 401-409.
Inaba, S.; Matsumoto, H.; Rieke, R. D. Journal of Organic Chemistry 1984, 49, 2093-2098.
Kavaliunas, A. V.; Rieke, R. D. Journal of the American Chemical Society 1980, 102, 5944-5945.
Tamao, K.; Kiso, Y.; Sumitani, K.; Kumada, M. Journal of the American Chemical Society 1972, 94, 9268-9269.
Tamao, K.; Sumitani, K.; Kumada, M. Journal of the American Chemical Society 1972, 94, 4374-4376.
Kiso, Y.; Tamao, K.; Kumada, M. Journal of Organometallic Chemistry 1973, 50, C12-C14.
Minato, A.; Tamao, K.; Suzuki, K.; Kumada, M. Tetrahedron Letters 1980, 21, 4017-4020.
Kumada, M. Pure and Applied Chemistry 1980, 52, 669-679.

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