Polyethylene heat shrinkable tube

Stock material or miscellaneous articles – Hollow or container type article – Shrinkable or shrunk

Reexamination Certificate

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Details

C428S035100, C428S036900, C428S036920

Reexamination Certificate

active

06887539

ABSTRACT:
The present invention improves the concentricity after expansion process of a heat shrinkable tube which is required to have a thin wall and hardness, and further aims to obtain elongation of 100% or more in a heat aging test, copperstability test, and heat shock test. The heat shrinkable tube satisfying such aim uses a medium- or high-density polyethylene that has a molecular weight distribution (Mw/Mn) of 30 to 55, an MFR of 0.05 to 0.2, and a specific gravity of 0.94 to 0.96. A medium- or high-density polyethylene obtained by combining an ethylene-vinyl acetate copolymer, ethylene-ethylacrylate copolymer, ethylene-methylacrylate copolymer, and ethylene-ethylmethacrylate copolymer may be used. More preferably, for an antioxidant, phenol-based and sulfur-based antioxidants are used together and zinc oxide is added.

REFERENCES:
patent: 3592881 (1971-07-01), Ostapchenko
patent: 3975039 (1976-08-01), Penneck et al.
patent: 4427725 (1984-01-01), Crofts
patent: 4576871 (1986-03-01), Oestreich
patent: 4576993 (1986-03-01), Tamplin et al.
patent: 5110638 (1992-05-01), Vogdes et al.
patent: 5250332 (1993-10-01), Kupczyk et al.
patent: 5324372 (1994-06-01), Chiotis
patent: 6060137 (2000-05-01), Akao
patent: 4-252246 (1992-09-01), None
patent: 9-95563 (1997-04-01), None
patent: P2000-186158 (2000-07-01), None
Fred Billmeyer, Jr., Textbook of Polymer Science, 1984, John Wiley & Sons, third edition, pp. 364-365.

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