Polyester resin foamed sheets

Details Polyester resin foamed sheets Polyester resin foamed sheets

1999-09-21

2002-04-02

Foelak, Morton (Department: 1711)

Stock material or miscellaneous articles

Hollow or container type article

Polymer or resin containing

C428S367000, C521S182000, C521S135000

Reexamination Certificate

active

06365249

ABSTRACT:

The present invention regards a polyester resin foamed sheet, which is heat-sealable, and suitable for the production of beverage and food containers, on which a design from which the shape of the container can be developed by folding can be stamped by pressing.
The invention includes the containers obtained from such sheet. It regards in particular a sheet having gas barrier properties suitable for the production of containers for beverages such as fruit juices, medium shelf-life milk, tea and similar.
BACKGROUND OF THE INVENTION
The materials employed till now for the production of beverage and food containers such as containers for fruit juices, milk or other, include substantially a functional layer of cardboard which gives to the container mechanical properties, in particular rigidity, and, adhered to the cardboard, in some cases, a layer of thin sheet of aluminum coated, on the side which comes into contact with the beverage or food, by a polyethylene film or similar polymeric material.
Containers produced with such multi-layer materials are difficult to recycle due to the different chemical nature of the various layers.
The recyclability of the material forming a food or beverage container is a most important requisite both from the point of view of savings that recycling allows to be obtained and from an ecological aspect.
The possibility of having a recyclable material is a very important topic in the sector.
Containers for beverages and liquids produced of polymeric materials exist but do not offer characteristics of rigidity comparable to those of cardboard and for this reason they do not result in being suitable to produce rigid containers. The containers obtained with such materials are comprised into the category of small sacks (pouches).
The attempt to obtain containers with the necessary rigidity by using polymeric materials has failed until now.
The rigidity in the containers is in function of the thickness of the wall and more precisely varies with the cube of the wall thickness.
The use of polymeric material such as polyolefins for the production of containers having sufficient rigidity would imply a thickness which is not economical and, furthermore, is not processable due to the difficulty in folding and sealing that one encounters in the container closing phase.
Another material such as foamed polystyrene is not employable due to its fragility when it is conformed into thin layers.
Known from the patent literature (U.S. Pat. No. 5,000,991) are rigid laminates, which are used for the preparation of thermoformed containers for victuals, formed of a sheet of foamed polyester material and of a film of the same nature as the sheet, or of other polymeric material. Known from EB-A-836937 are semi-rigid laminates having a thickness of 0.5 to 1.5 mm comprising a layer of polyester resin foam having a density of 0.7 to 1 g/cm
3
on which a layer having gas barrier properties, made of a polymeric material different from that of the layer in polyester foam, is adhered.
The laminates are used for the preparation by thermoformation of articles for packaging.
Materials comprising a layer in polyester foam capable of being creased to form, by folding according to the design pressed on the material, the shape of the container, are not known in patent literature.
The capability of a mono-layer or multi-layer polymeric foamed material, to be creased with a design set to develop by folding the shape of a container, and the foldability of the material according to such a design, constitute indispensable requirements for the production of beverage and food containers when using the creasing and folding technique.
A material is suitable for creasing if the design pressed on it remains stable over time and if when stamping such design, breakage which could impair the possibility of folding the material does not occur.
Moreover the material must be heat-sealable so as to make possible the closure of the container.
It has now unexpectedly been found a polymeric material of polyester resin foam, which is suitable for the production of beverage and food containers, satisfying the above mentioned creasing requirements, and which presents rigidity sufficient to substitute cardboard.
SUMMARY OF THE INVENTION
The foamed material of the present invention comprises, or is made of, a substantially amorphous (containing less than 5% crystallinity) foamed sheet obtained from a polyester resin, having crystallization rate such that, by heating at 120° C. for 5 minutes, the crystallinity does not reach values higher than 15% and preferably does not reach values higher than 10%.
DETAILED DESCRIPTION OF THE INVENTION
The polyester resin preferably used for the preparation of the foamed sheet is a copolyethylene terephthalate in which from 2 to 20% in moles of units of terephthalic acid are substituted by units deriving from isophthalic and/or naphthalene-dicarboxylic acids.
Preferably, the copolyethylene terephthalate comprises from 4 to 10% of units deriving from isophthalic acid.
With the aim of improving the gas barrier properties of the foamed sheet, the same can be coated with a polyester resin film or other material having gas barrier properties.
In the case in which the sheet is covered with a polyester film, the barrier properties of the latter are conferred by subjecting the film to surface treatment giving it barrier properties or by the application of materials with barrier properties such as aluminum and oxides of aluminum and silicon (Al
2
0
3
and SiO
x
).
A representative surface treatment is the lacquering of the film with a layer of lithium or potassium polysilicate. The treatment allows the realization of very slow oxygen permeation rates, which can be 0.3 ml/m
2
/24 h/atm or less.
The application of layers of aluminum and oxides of Al and/or Si is carried out according to known methods.
The surface treatments and the deposition of barrier materials are selected and carried out in a way such as to confer to the polyester film oxygen permeability properties generally lower than 70 ml/m
2
/24 h/atm (ASTM 1434). In the case of a film metallized with Al or coated with oxides of Al and/or Si, the rate of oxygen permeability can be reduced to values lower than 0.3 ml/m
2
/24 h/atm. Values lower than 10 ml/m
2
/24 h/atm are preferred. Polyester films metallized with aluminum are commercially obtainable under the name of Nu Roll of Nurol S.p.A. (Nu Roll is a registered trade mark of Nurol S.p.A.).
In the case where a film with barrier properties is adhered on the sheet, the untreated side of this film is the one which comes into contact with the beverage or food inside the container.
It is also possible, and this is in function of the various requirements, such as for example printing with inks or other, to use a film corresponding to the above requirements as external layer having the foamed sheet onto which the film is adhered as the internal layer.
The adhesion of the film with barrier properties or other film on the foamed sheet, can be realized according to known methods by gluing or heat-lamination or by coextrusion.
The foamed sheet of this invention has a thickness between 0.2 and 3 mm, most preferably between 0.2 and 1.5 mm. The density of the sheet is lower than 700 kg/m
3
and is preferably between 10 and 500 kg/m
3
, most preferably between 100 and 200 kg/m
3
.
It is also possible to cover the foamed polyester sheet with a layer of a heat-sealable polymer different from the polyester resin.
The preparation of the foamed sheet is carried out according to known extrusion-expansion methods.
A preferred method is that disclosed in U.S. Pat. No. 5,362,763, the description of which is herewith incorporated by reference.
Other methods are those disclosed in U.S. Pat. No. 5,362,763, the description of which is also incorporated by reference.
The rigidity of the foam sheet is in function of the thickness of the same: it increases (not proportionally) with the thickness. The use of inorganic fillers (usable up to about 20% by weight) allows an increase of the sheet rigidity. Example

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