Polyester of para-hydroxy benzoic acid, 1,2-bis(para-carboxy phe

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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Details

528194, C08G 6360, C08G 6366

Patent

active

042385997

ABSTRACT:
A novel polyester is provided which has been found to exhibit an anisotropic melt phase at a temperature which enables it readily to undergo melt processing to form quality fibers, molded articles, etc. The polyester of the present invention is different in character than polyesters of the prior art and includes as essential ingredients moieties derived from para-hydroxy benzoic acid, 1,2-bis(para-carboxy phenoxy)ethane, terephthalic acid, and substituted hydroquinone in the proportions indicated. The polyester of the present invention generally can be more economically produced than polyesters of the latter three moieties (two of which are relatively expensive) while surprisingly yielding an anisotropic melt of relatively low viscosity at a desirable temperature for melt processing in spite of the substantial concentration of relatively stiff para-oxybenzoyl moieties which contribute to the overall nature of the resulting polyester. In a preferred embodiment the polyester is capable of undergoing melt processing at a temperature below approximately 300.degree. C., and in a particularly preferred embodiment at a temperature below approximately 290.degree. C. (e.g., with standard equipment commonly used to melt process polyethylene terephthalate).

REFERENCES:
patent: 3991013 (1976-11-01), Pletcher
patent: 3991014 (1976-11-01), Kleinschuster
patent: 4067852 (1978-01-01), Calundann
patent: 4083829 (1978-04-01), Calundann et al.
patent: 4118372 (1978-10-01), Schaefgen
patent: 4130545 (1978-12-01), Calundann
patent: 4140846 (1979-02-01), Jackson, Jr. et al.

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