Polyester-amides prepared from polymalonates and isocyanates

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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2521883R, 260 25AN, 260 25AC, 260 25AZ, 260 75NC, 260 75NK, 260 75NP, 260 75NQ, 260 75N, 260860, C08G 1834, C08G 1842

Patent

active

040061221

ABSTRACT:
Poly(ester amides) are obtained by heating a hydroxyl-containing or hydroxyl-free polyester of malonic acid with an organic polyisocyanate in the presence of a basic catalyst. Crosslinking of the polyester takes place by reaction of the isocyanate with the active hydrogen of the CH.sub.2 group of the malonate to give amide linkages, in addition to formation of urethane linkages in the case where the polyester contains free hydroxyl groups. The products range from elastomeric materials, where the isocyanate is in the form of an isocyanate-terminated prepolymer derived by reaction of an organic polyisocyanate with a polyol, to more rigid plastics where the isocyanate is a "simple" isocyanate, i.e. not in prepolymer form.

REFERENCES:
patent: 2625531 (1953-01-01), Seeger
patent: 2970119 (1961-01-01), Caldwell
patent: 3079350 (1963-02-01), Bernstein
patent: 3296211 (1967-01-01), Winkler et al.
patent: 3450673 (1969-06-01), McKillip

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