Polydithiocarbamate resin

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

Reexamination Certificate

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Details

C210S660000, C210S666000, C210S679000, C210S681000, C528S049000, C528S071000, C558S235000, C558S236000, C558S237000

Reexamination Certificate

active

07030205

ABSTRACT:
The present invention is directed to a solid chelating resin consisting of a reactive hydrophobic backbone having pendent carbodithioic groups. Preferably the resin is a poly(dithiocarbamate) containing no tertiary nitrogen groups. The invention is also directed to a novel process for making a chelating resin involving a) reacting a nucleophilic compound with carbon disulfide in a suitable solvent, to form a carbodithioic acid, b) neutralizing the carbodithioic acid with a base to form a carbodithioic acid salt; and c) reacting said carbodithioic acid salt with a crosslinking reagent in a suitable solvent to form a solid chelating resin. The chelating resin is useful in removing metals and cationic compounds from effluent streams.

REFERENCES:
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patent: 4518760 (1985-05-01), Smith et al.
patent: 4578195 (1986-03-01), Moore et al.
patent: 5695882 (1997-12-01), Rosenberg et al.
patent: 5997748 (1999-12-01), Rosenberg et al.
patent: 6063286 (2000-05-01), Steuerle et al.
patent: 6153795 (2000-11-01), Bicak
patent: WO 98/11066 (1998-03-01), None
Miyazaki, Akira and Barnes, Ramom M., “Differential Determination of Chromium (VI) —Chromium (III) with Poly(dithiocarbamate) Chelating Resin and Inductively Coupled Plasma —Atomic Emission Spectrometry”, Anal. Chem. 1981, 53, 364-366.
Miyazaki, Akira and Barnes, Ramom, M., “Complexation of Some Transition Metals, Rare Earth Elements, and Thorium with a Poly(dithiocarbamate) Chelating Resin”, Anal. Chem. 1981, 53, 299-304.
Horvath, Zs. And Barnes, Ramon, M., “Characterization of Functional Group Complexation of a Poly(dithiocarbamate) Chelating Resin”, Anal. Chem. 1986, 58, 725-727.

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