Polybutadiene composition and process for producing same

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526 78, 526 81, 526 86, 526 93, 526 94, 526136, 526138, 526139, 526140, 526141, 526142, 526335, 525232, 525236, 428402, C08F 3606, C08F 218

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054688221

ABSTRACT:
A 1,2-polybutadiene composition having an excellent reinforcing effect for rubber and synthetic resin materials including at least two polybutadiene components different in melting point from each other and each having, as a main structure, a 1,2-polybutadiene structure, produced by polymerizing a 1,3-butadiene-containing monomer in a water-containing polymerization system in the presence of a catalyst comprising a transition metal compound, an organic compound of one of the Group I to III metals, and one of carbon disulfide, phenyl isothiocyanate, and xanthic acid compounds, while adding a melting point-regulating agent comprising at least one of ketones, aldehydes, alcohols, esters, nitriles, sulfoxides, amides, and phosphoric acid esters in one or two or more separate adding operations or a continuous adding operation.

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patent: 4790365 (1988-12-01), Sandstrom et al.
patent: 5011896 (1991-04-01), Bell et al.
Hackh's Chemical Dictionary (4th ed.) McGraw-Hill, Inc., N.Y., 727 (1969).

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