Polyarylene sulfide and preparation thereof

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From sulfur-containing reactant

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Details

528378, 528379, 528388, C08G 6540, C08L 7110

Patent

active

053843916

ABSTRACT:
A process for preparing polyarylene sulfides which comprises providing at least one cyclic arylene sulfide oligomer of the formula ##STR1## wherein S represents a sulfur atom, groups Ar, which may be the same or different, represent each an arylene radical having 6-24 carbon atoms, groups R, which may be the same or different, represent each a C.sub.1 -C.sub.12 alkyl radical, or a C.sub.1 -C.sub.12 alkoxy radical, or a primary or secondary amino group, n is an integer of from 2 to 50, and m is an integer of from 0 to 15, and heating said cyclic oligomer I in the presence of a ring opening polymerization catalyst so as to form polyarylene sulfide. The process produces polyarylene sulfides improved in chemical, physical and mechanical properties.

REFERENCES:
patent: 3755268 (1973-08-01), Fritze
patent: 4605731 (1986-08-01), Evans et al.
patent: 4740583 (1988-04-01), Brunelle et al.
patent: 5097008 (1992-03-01), Krabbenhoft et al.

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