Polyamide-polyurea polymers by the RIM process

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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264 53, 264 54, 2643286, 264DIG83, 528 67, 528 73, 528 75, 521163, C08G 1830, C08G 1832

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045529450

ABSTRACT:
Polyamide-polyurea containing polymers are disclosed that are derived from the reaction of (A) an organic polyisocyanate; (B) an organic compound having at least two active hydrogen containing groups; and (C) about 15 to about 160 parts per 100 parts of said (B) of a chain extender combination comprising (i) a particular enamine and (ii) an aromatic diamine and optionally (iii) an extender diol wherein the ratio of equivalents of (A) to total equivalents of (B) and (C) is within the range of about 0.90:1 to 1.10:1.
The polymers find particular utility in the preparation of RIM parts having excellent physical properties. At the same time, the polymers are characterized by slower gel times than prior art aromatic diamine extended polymers thereby allowing the filling of larger molded parts.

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