Polyamic acid to polyimide conversion by microwave heating

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415781, 20415789, C25B 300

Patent

active

054531616

ABSTRACT:
An intermolecular and/or intramolecular non-foamed polyimide is prepared by heating an aromatic tetracarboxylic acid or dianhydride thereof and an aromatic diamine thereby preparing a polyamic acid, and then subjecting the polyamic acid in the solid phase in the absence of solvent to focused microwave radiation, thereby preparing the polyimide product.

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Lewis et al. "Accelerated Imidization Reactions Using Microwave Radiation", Journal of Polymer Science, Part A: Polymer Chemistry, vol. 30, 1647-1653 (no month) (1992).
Thermal Solution Reactions, Cure Kinetics and Mechanical Behavior of Electromagnetically Processed Polyimides, Lewis et al, pp. 174-175. (no date).

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