Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1987-09-11
1989-07-11
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
528 34, C07F 710
Patent
active
048474002
ABSTRACT:
A polyalkoxysilylalkylenedisilazane of the formula ##STR1## and a polyalkoxysilylalkylenesilylamine of the formula ##STR2## where x is 0 or 1; R is a saturated alkyl or aryl radical or mixture of radicals; R' is alkyl, aryl, or cellosolve (R) 2-alkylethanol radical, or mixture of radicals; R" is hydrogen, alkyl, aryl, or arylalkyl radical or mixture of radicals; and A is a divalent hydrocarbon radical having 2 to 20 carbon atoms; and a method for their manufacture by the platinum catalyzed addition of an alkenyl- functional disilazane or silylamine with an alkoxy-functional silicon hydride is disclosed. The silylamine can also be produced by the platinum catalyzed addition of a SiH functional silazane of silylamine and an alkenyltrialkoxysilane. The polyalkoxysilylalkylenedisilazane and the polyalkoxysilylalkylenesilylamine can be reacted with a silanol containing polyorganosiloxane such as a hydroxyl endblocked polydiorganosiloxane in the presence of an acidic catalyst to give a polyalkoxysilyl terminated polydiorganosiloxane in which the terminal groups are bonded to the polymer through an alkylene linkage.
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Krahnke Robert H.
Saam John C.
Dow Corning Corporation
Elliott Edward C.
Shaver Paul F.
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