Polyaldaramide polymers useful for films and adhesives

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carbohydrate or derivative as a reactant

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527312, 528335, 528337, 528338, 528340, 528341, 528342, C08G 6926, C08G 6940

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active

054342333

ABSTRACT:
Polymers of glucaric or xylaric acid with diprimary amines containing at least one heteroatom in the main chain form films when cast from aqueous solution and show adhesive properties. Unexpectedly, analogous polymers prepared using galactaric acid, an isomer of glucaric acid, do not form satisfactory films when cast from aqueous solution and exhibit poor or no adhesive properties. Copoly(aldaramides) comprising galactaric acid residues and either glucaric acid or xylaric acid residues, when prepared by reacting an equivalent weight of an activated galactarate with a product formed by reaction of two equivalents of a diprimary heterohydrocarbylenediamine with one equivalent of either an activated xylarate or glucarate also afford film-forming polymers which exhibit adhesive properties.

REFERENCES:
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patent: 4833230 (1989-05-01), Kiely
patent: 5053484 (1991-10-01), Speranza
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patent: 5329044 (1994-07-01), Kiely
F. W. Billmeyer, "Textbook of Polymer Science", 2nd ed., Wiley Interscience, New York, pp. 224-225, 229 & 230 (1971).

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