Polyacetylene composite process for production thereof, and meth

Chemistry: electrical current producing apparatus – product – and – Process of cell operation

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429197, 429213, 2521821, 252500, 4274071, 204 75, H01M 460, H01M 616

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active

046861602

ABSTRACT:
Polyacetylene composite comprising a polyacetylene polymer coated with at least one ionic organic compound such as alkali metal alkoxide type compounds of 1,2-diol, semicarbonic ester derivatives of 1,2-diol, and ortho-ester derivatives; a process for the production of the above composite characterized by applying a solution of the above ionic organic compounds to the polyacetylene polymer; a process for the production of the above composite characterized by placing the polyacetylene polymer as an electrode in an electrolyte containing a cyclic carbonic ester compound and an alkali metal ion and electrochemically reducing the cyclic carbonic ester compound; and a process of using an n-doped polyacetylene composite as a negative electrode active substance for a secondary battery. The ionic organic compound provides high stability to the n-doped polyacetylene and therefore the secondary battery using it as a negative electrode active substance has outstanding protracted charge-discharge cycle properties, self-discharge properties, and voltage-maintaining properties.

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patent: 4419277 (1983-12-01), Myers
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patent: 4502981 (1985-03-01), Delannoy et al.

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