Poly(monoperoxycarbonates)

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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525313, 525387, 525451, 526346, 558263, C08F 436, C08F 438, C08F 800, C07C 6996

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057601496

ABSTRACT:
Poly(monoperoxycarbonates) of the structure: ##STR1## where R, R.sup.1 and n are defined in the summary of the invention such as 1,1,1-tris(t-butylperoxycarbonyloxymethyl)ethane, intermediates for their preparation as well as processes for their preparation and use are disclosed. The monoperoxycarbonate compounds are useful in initiating the polymerization of ethylenically unsaturated monomers, particularly styrene, curing of unsaturated polyester resins, and in modifying the molecular weight of polymers such as by crosslinking or controlled chain degradation.

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92:164324 Chem. Abs. Jun. 1980 Ladousse et al.
71:123928 Chem. Abs. Dec. 1969 Komai et al.
99:88729 Chem. Abs. Nov. 1983 Sanken Kako Co.

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