Poly(iminomethylene) copolymer from isocyanides

Details Poly(iminomethylene) copolymer from isocyanides Poly(iminomethylene) copolymer from isocyanides

1985-09-30

1987-11-03

Anderson, Harold D.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymer of an ethylenically unsaturated reactant with a...

528422, 558302, C08G 8300

Patent

active

047044497

ABSTRACT:
A poly(vinyliminomethylene) polymer having at least one recurring structural unit of the formula: ##STR1## wherein R and R', which are the same or different, are each hydrogen, a C.sub.1 -C.sub.8 alkyl group or C.sub.3 -C.sub.7 cycloalkyl group which alkyl or cycloalkyl groups are unsubstituted or substituted by lower alkyl or alkoxy groups or which contain up to four non-catenated oxygen atoms, a C.sub.2 -C.sub.8 alkenyl group or a C.sub.5 -C.sub.7 cycloalkenyl group which is unsubstituted or substituted by lower alkyl or alkoxy groups, a phenyl group or naphthyl group which is unsubstituted or substituted by lower alkyl or alkoxy groups, with the proviso that at least one of R and R' be a substituent other than hydrogen; R" is hydrogen; and n has a value such that the weight-average molecular weight is in the range of about 2,000 to 400,000 as determined by gel permeation chromatography.

REFERENCES:
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Proc. IUPAC, Macromol. Symp., 28th, 1982, p. 451.
Kogyo Kagaku Zasshi, vol. 70, 10 (1967), pp. 1822-1825.
Nippon Kagaku Zasshi, vol. 89, 9, (1968), pp. 78-80.
CA 70:47921(m); "Polymerization of Isocyanides II. Cationic Copolymerization of Isocyanides" and Nippon Kagaku Zasshi, vol. 89, 9 (1968) and English language version corresponding thereto. Yamamoto et al.
CA 68:10558(v): "Copolymerization of Isonitriles by Boron Trifluoride Ethyl Etherate," by S. Iwatsuki et al. and Kogyo Kagaku Zasshi, vol. 70, 10 (1967) pp. 1822-1825 and English Language version thereof.
CA 99:195702(e): "Poly(Iminomethylenes) Charge Transfer Interactions by Oostveen, F. A. et al.

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