Poly(heterocyclic) polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From ketone or ketene reactant

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528226, 528229, 528289, 528290, 528291, 528294, 528295, 528298, 528299, 528300, 528335, 528373, 528403, 525437, 525461, 525462, 525470, 525471, 525534, C08G 802

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049141767

ABSTRACT:
Novel thermoplastic polymers of relatively high glass transition temperatures are characterized by five-carbon moieties having a keto group in the 3-position alternating with bis(benzoheterocyclic) moieties. The polymers are produced by reaction of a keto-C.sub.5 source, selected from 4-oxoheptanedioic acid compounds or a 1,6-dioxa [4.4] spirodilactone, with a bis(ortho-phenylene amine) compound. Further cyclization of the initial polymer product or reaction of a bis(ortho-phenylenediamine) provides a polymer having a hexacyclic repeating unit.

REFERENCES:
patent: 3969294 (1976-07-01), Papouchado
patent: 4100140 (1978-07-01), Zahir et al.
patent: 4663464 (1987-05-01), Hoekstra
patent: 4800231 (1989-01-01), Wang
patent: 4847388 (1989-09-01), Wang

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