Poly(ethylene phenylene ethynylene silylenes) comprising an...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ethylenically unsaturated reactant admixed with either...

Reexamination Certificate

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C526S285000, C528S035000, C528S043000

Reexamination Certificate

active

06919403

ABSTRACT:
The present invention relates to polymers of poly(ethynylene phenylene ethynylene silylene) type comprising an inert spacer in the main chain of the polymer.The invention also relates to processes for preparing said polymers and to the cured products that may be obtained by heat-treating said polymers.The polymers according to the invention may be used especially in matrices for composites.

REFERENCES:
patent: 5243060 (1993-09-01), Barton et al.
patent: 6703519 (2004-03-01), Buvat et al.
patent: 0 617 073 (1994-09-01), None
patent: 2 798 662 (2001-03-01), None
patent: WO 200119899 (2001-03-01), None
Corriu, et al., “Synthesis of Poly(alkynylsilanes) having Various aromatic Groups in the Backbone”, Journal of Polymer Science Part C, Polymer Letters, 28, No. 13, pp. 431-437 (Dec. 1990).
Itoh, et al., New Highly Heat-Resistant Polymers Containing Silicon: Poly(silyleneethynylenephenyleneethynylene)s, Macromolecules, 30, pp. 694-701 (1997).
Liu, et al., “Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes”, Can J. Chem, vol. 68, pp. 1100-1105 (1998).
Kuroki, et al., “Thermosetting mechanism Study of Poly(phenylsilylene)ethynylene-1, 3-phenyleethynylenel by Solid-State NMR Spectroscopy and Computational Chemistry”, Macromolecules, 31, pp. 2804-2808 (1998).
Abstract of JP 7-126394.
Abstract of JP 10-110037.

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