Poly(etheramide) segmented block copolymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528338, 528339, 528347, C08G 6926

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active

053996631

ABSTRACT:
An amine terminated random copolymer containing ethylene oxy/propylene oxy segments may be reacted with hexamethylene diamine and adipic acid monomers to make improved poly(etheramide) segmented block copolymers. Ordinarily, poly(propylene glycol) diamines tend to phase separate under these conditions and polyamide-6,6 could not be so modified. The resultant poly(etheramide) segmented block copolymer has improved impact performance, reduced modulus and lower glass transition as contrasted with the non-modified polyamide-6,6.

REFERENCES:
patent: 2359867 (1944-10-01), Martin
patent: 5053484 (1991-10-01), Speranza et al.
patent: 5086162 (1992-02-01), Speranza et al.
Chemical Abstracts, vol. 31:769 9 6/(1946).
S. Iwabuchi, et al., "Darstellung und Eigenschaften von Copolyamiden mit Oxyethylenegruppen in definierter Sequenz," Makromol Chem., vol. 183, 6/(1982) pp. 1427-1433, Summary.
J. R. Flesher, Jr., "Polyether Block Amide: High Performance TPE," Modern Plastics, Sep., 1987, pp. 100-110.

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