Poly(4,5,9,10-tetrahydropyrene-2,7-diyl) derivatives and their u

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4284111, 428457, 428917, 313504, 313506, 25230116, 25230135, 526 90, 526171, 526 28, 526281, 526296, 528397, H05B 3312, C09K 1106

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057284806

ABSTRACT:
Poly(4,5,9,10-tetrahydropyrene-2,7-diyl) derivatives of the formula (I) ##STR1## where the symbols R.sup.1 to R.sup.4 have the following meanings: R.sup.1, R.sup.2, R.sup.3, R.sup.4 are identically or variously H, a straight-chain or branched alkyl chain containing 1 to 22 carbon atoms, it being possible for one or more nonadjacent CH.sub.2 groups also to be replaced by --O--, --COO--, --OOC-- and/or phenylene, aryl or aryloxy groups, it being possible for the aromatic to be substituted by C.sub.1 -C.sub.22 -alkyl, C.sub.1 -C.sub.22 -alkoxy, Br, Cl, F, CN, and/or NO.sub.2, Br, Cl, F, CN, NO.sub.2, or carboalkoxy containing 2 to 23 carbon atoms;
n is 10 to 150,
are suitable as electroluminescence materials.

REFERENCES:
M. Kreyenschmidt et al., "A New Soluble Poly(p-phenylene) with Tetrahydropyrene Repeating Units", Macromolecules, vol. 28, No. 13, Jun. 19, 1995, pp. 4577-4582.
Chemical Abstracts, vol. 122, Jan. 1995, Columbus, Ohio, by M. Kreyenschmidt, et al., entitled "A new Soluble Poly(p-pheny-lens) with Tetrahydropyrene Repeating Units", p. 11.
Synthetic Metals by Grem et al., entitled "Blue Electroluminescent Device Based on a Conjugated Polymer", pp. 383-389, 1992.
J. Chem. Soc., Chem Communications by Ballard et al., entitled "A Bioteh Route to Polyphenylene", pp. 954-955, 1983.
PMSE-Meeting Chicago (1993), vol. 69, by Klavetter et al., entitled "Photoluminescence andElectroluminescence of Transparent Polyphenylene Derivatives", pp. 153-154.
Journal of Polymer Science, Part A. Polymer Chemistry, vol. 31, by Fukada et al., "Synthesis of Fusible and Soluble Conducting Polyfluorene Derivatives and their Characteristics", pp. 2465-2471, 1993.
Japanese Journal of Applied Physics, vol. 30, No. 11B,Nov. 191, by Ohmori et al., entitled "Blue Electroluminescent Diodes Utilizing Poly(alkylfluorene)", pp.1941-1943.

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