Plugged flow 2D chromatography

Measuring and testing – Liquid analysis or analysis of the suspension of solids in a... – Content or effect of a constituent of a liquid mixture

Reexamination Certificate

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Reexamination Certificate

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08074494

ABSTRACT:
The invention provided is a split-free nano-liter flow liquid chromatography system comprising at least a first and a second chromatographic column connected in series, wherein an autosampler is provided and programmed to inject samples and eluent solutions of increasing eluent concentration for gradually eluting analytes from the first column into the second column (without adversely affecting separation in the second column), said solutions segmented from the mobile phase of the liquid chromatography system by air plugs.

REFERENCES:
patent: 6613235 (2003-09-01), Anderson et al.
patent: 2006/0157647 (2006-07-01), Siuzdak et al.
patent: WO 2004/017040 (2004-02-01), None
Gu et al., “Capillary array reversed-phase liquid chromatography-based multidimensional separation system coupled with MALDI-TOF-TOF—MS detection for high-throughput proteome analysis,”Journal of Proteome Research(2006) 5: 3186-3196.

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