Stock material or miscellaneous articles – Article having latent image or transformation
Reexamination Certificate
2001-01-16
2003-07-22
Loney, Donald J. (Department: 1772)
Stock material or miscellaneous articles
Article having latent image or transformation
C428S035200, C428S035700, C428S916000, C426S087000, C426S383000, C426S415000, C283S072000, C283S095000, C283S107000, C206S807000
Reexamination Certificate
active
06596354
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to plastics film useful for packaging or for lamination to paper or board to form packaging or promotional material and to the preparation and use of such film. In particular, it relates to plastics film useful for security packaging having a feature which is not apparent to the eye but which can readily be revealed in a test for authenticity. It also relates to the use in the identification of goods of dyestuffs capable of undergoing a clearly visible colour change when contacted with a colour-developing material and to a process for testing the authenticity of packaged goods.
BACKGROUND ART
Invisible inks have long been known and have been used or suggested for use in various covert marking procedures. For example, U.S. Pat. No. 5,424,266, U.S. Pat. No. 5,476,830 and U.S. Pat. No. 5,532,200 describe a latent image printing method and apparatus in which a substrate with one main surface has a covering comprising a dye defining a background colour. When the dye is mixed with a colour developer they produce a spectral response which is visible relative to the background colour. There is a continuous coating over the covering which is non-porous and solvent-resistant with respect to the colour developer. U.S. Pat. No. 5,421,809 and U.S. Pat. No. 5,516,362 describe a security marking method comprising marking a portion of a substrate by applying a first marking fluid which is invisible when illuminated by both visible light and ultraviolet light and activating the marked portion by applying a second marking fluid thereon. The second marking fluid is reactable with the first marking fluid to be invisible when illuminated by visible light and fluorescent when illuminated by ultraviolet light.
U.S. Pat. No. 5,595,590 describes a method for authenticating a document or article comprising applying a mixture of a carrier, a leuco dye and an activator to a surface of a document or article, wherein the leuco dye and activator react in response to a rubbing force applied to the surface so as to change colour.
GB-A-1593172 describes an apparatus for applying written or drawn information onto image carriers for overhead projectors, comprising an image carrier in film or plate form which includes at least one coloured compound, as well as a writing or drawing marker, the writing or drawing fluid of which contains at least one colourless compound. This colourless compound reacts with the coloured compound to produce a colour change.
DISCLOSURE OF THE INVENTION
We have found that a dyestuff capable of undergoing a clearly visible colour change when contacted with a colour-developing chemical is useful in the identification or authentication of goods when it is dispersed in the body of a plastics film.
The plastics film can be used in packaging goods, generally as the outermost layer of packaging over at least part of the surface area of the packaged goods or in a position such that it can easily be contacted by the colour-developing chemical. The plastics film can be used as a label or seal affixed to goods, for example a seal which has to be broken to open the package. The plastics film can be used as the outer(most) layer of laminated packaging.
The invention also includes a process for testing the authenticity of packaged goods, characterised in that the goods are packaged in packaging material including a plastics film having a dyestuff dispersed in the body of the plastics film, said dyestuff being capable of undergoing a clearly visible colour change when contacted with a colour-developing chemical, and the said plastics film is marked with the colour-developing chemical to produce a coloured mark on the package.
The invention also includes a plastics film having a dyestuff dispersed in the body of the plastics film, characterised in that the dyestuff is a latent dyestuff which is colourless and invisible to the eye under ambient conditions for use of the film but which forms a clearly visible colour when contacted with a colour-developing chemical.
The system of the present invention has the advantage over invisible ink security marking systems of being more difficult to replicate, and hence more secure, and also more durable whilst being just as easy to mark when testing for authenticity. The dyestuff is distributed throughout the film, which is a self-supporting film, rather than simply being printed on the surface, and access to the film can be restricted to reputable manufacturers, for example manufacturers of expensive branded luxury goods and products or compact discs or computer software. Film having an area printed with invisible ink is often detectable because a slight difference of gloss in the printed area is visible, whereas dispersion of the dyestuff in the body of the film in accordance with the invention does not indicate to a counterfeiter that the dyestuff acts as a security check.
The plastics film can for example be a cast film such as a cast cellulose acetate film or can be an extruded film such as a polyolefin film, for example polyethylene or polypropylene, or a polyester film, for example polyethylene terephthalate. The film can be a clear, matt or semi-matt film. The film can be crosslinked, for example crosslinked cellulose acetate film. The film can contain any of the additives known for incorporation in film, provided that these do not obscure the colour developed by the dyestuff and colour-developing chemical. Cellulose acetate film can for example contain a plasticiser, for example 10 to 25% by weight of a phthalate ester plasticiser such as diethyl phthalate. The thickness of the film is generally in the range 5 to 500 microns, more usually 10 or 15 microns up to 50 or 100 microns. For example, film for lamination over print, e.g. for lamination over paperboard packaging, may have a thickness of 10 to 25 or 40 microns and film for other uses such as labels and seals or for window packaging may have a thickness of 25 to 75 microns.
The dyestuff is preferably a latent dyestuff which is colourless and invisible to the eye under ambient conditions for use of the film but which forms a clearly visible colour when contacted with a colour-developing chemical. The film can thus appear as an ordinary transparent or translucent film in normal use. The dyestuff can alternatively form a coloured film under ambient conditions which is changed to colourless or to a different colour by the colour-developing chemical.
The dyestuff can for example be an acid/base indicator, preferably a latent dyestuff indicator which is inconspicuous at ambient pH for use of the film (usually neutral pH) but which develops colour on contact with strong acid or strong base. Phenolphthalein, for instance, is colourless at neutral pH but develops a vivid pink colour when marked with alkali, and thymolphthalein is colourless at neutral pH but develops a blue colour when marked with alkali. The colour development system is preferably reversible in most cases so that, after the coloured mark has been observed, the marked area can be contacted with a chemical which reacts with the dyestuff to change it back to its original colour, for example the colourless and invisible form of a latent dyestuff. As a result, the marked area is indistinguishable from the rest of the film. In other words, the packaged goods can be authenticated but then sold unmarked. Acid/base indicators are generally reversible. A pink mark on a film containing phenolphthalein will vanish when overmarked with an acid. The latent dyestuff can alternatively be a leuco dye. 4-Nitrophenol and 3-nitrophenol are examples of dyes which change colour on application of acid, being yellow at neutral pH and changing to olive or green at acidic pH. The dyestuff incorporated in the film can be a material sold commercially as a colour developer, with the corresponding coupler being applied as the colour-developing chemical of the invention. For example, the material sold as “Color Developer CD3” for use in coloured photographic film base, believed to be a salt of 3-methyl-N-(2-methylsulphonamido
Heald Gwynneth Anne
Law Paul William
Longdon Tony
Acordis Acetate Chemicals Limited
Howson and Howson
Loney Donald J.
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