Plasticized polyester for shrink film applications

Stock material or miscellaneous articles – Structurally defined web or sheet – Discontinuous or differential coating – impregnation or bond

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528272, 528307, 528308, 5283086, 525437, 5254445, 524127, 524313, 524318, 524605, 264211, 264291, 428119, 428221, 428357, B32B 300, C08F28300, C08G 6391

Patent

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058243984

ABSTRACT:
This invention relates to polyester/plasticizer blends which are useful as heat-shrinkable films or sheets in low temperature shrink packaging applications. The heat-shrinkable films or sheets comprise a blend of (A) 90 to 99 weight percent of a polyester having a glass transition temperature of 40.degree. C. to 150.degree. C. and an inherent viscosity of 0.5 to 1.2 dL/g and (B) 1 to 10 weight percent of a plasticizer selected from a C.sub.5 to C.sub.35 monoglyceride prepared from the reaction of glycerol and a fatty acid having 4 to 30 carbon atoms, wherein the combined weights of (A) and (B) total 100 percent. The polyester comprises a dicarboxylic acid component comprising repeat units from at least 80 mole percent of an aromatic dicarboxylic acid having 8 to 14 carbon atoms and a diol component comprising repeat units from at least 10 mole percent of 1,4-cyclohexanedimethanol, based on 100 mole percent dicarboxylic acid and 100 mole percent diol.

REFERENCES:
patent: 4963418 (1990-10-01), Isaka et al.
patent: 4996291 (1991-02-01), Yoshinaka et al.
patent: 5534570 (1996-07-01), Shih et al.
patent: 5589126 (1996-12-01), Shih et al.

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