Plasticized cellulose polymers

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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102290, 106169, 149 10, 149 11, 149 12, 149 197, 536 68, 536 85, C08G 1810

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043628680

ABSTRACT:
Plasticized cellulose polymers comprise a base polymer having a chain of .beta.-anhydroglucose units joined by ether linkages and having ether substituents, with at least one of the units being additionally substituted, by esterification of at least one hydroxyl group, by at least one ester group, which contains at least two carbon atoms and is chemically unreactive.
Preferably the ester group contains four or more, most preferably five, carbon atoms. The carbon chains of the ester groups may be straight or branched.
These internally plasticized celluloses may be prepared by, for example, reacting the base polymer with a carboxylic acid in xylene or with an acid chloride or anhydride in pyridine. They are useful in particular as inhibitor coatings for rocket motor propellants and in general wherever cellulose polymers are employed.

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