Coating processes – Solid particles or fibers applied – Applying superposed diverse coatings or coating a coated base
Reexamination Certificate
1999-06-02
2002-09-10
Parker, Fred J. (Department: 1762)
Coating processes
Solid particles or fibers applied
Applying superposed diverse coatings or coating a coated base
C427S203000, C427S370000, C427S391000, C427S420000
Reexamination Certificate
active
06447841
ABSTRACT:
FIELD OF THE INVENTION
This application relates to ink jet printed images and to a method for providing water resistance, some lightfastness, and scratch resistance to wide format and narrow format images such as poster, banners, and photos in both indoor and outdoor environments.
BACKGROUND OF THE INVENTION
Ink jet printed images in wide format size are often laminated providing water resistance. These types of laminations are extremely costly and it is desirable to secure a less costly and easier method which could eliminate the need to use a professional print shop. Providing water resistance would allow one to hang posters or banners for use in outside environments. This invention could also be used for products of various sizes which require water resistance, such as business cards or wallpaper. The invention provides water resistance to ink jet prints of any size. This is extremely beneficial in that it overcomes a shortcoming of ink jet printing when compared to laser printing. The end product produced is durable, holds up in all weather conditions, and is long lasting. The end user can impart the water resistance easily on their own, as well as have it imparted in commercial establishments.
Several prior coatings have been disclosed or suggested for ink jet papers, as described in the following references.
U.S. Pat. No. 4,900,620, Tokita et al, describes a material with bright white pigments which provide quick absorption, good color image, circular dots, and waterproofness. The waterproofness is provided by a water soluble cationic polymer. These white pigments are not plastic pigments and waterproofness is not provided by plastic pigments as is described by the novel invention set forth herein. Further, the patent does not discuss or mention any requirement to heat the coating, that is the printed image which is a step required for finishing the printed product.
U.S. Pat. No. 4,902,568, Morohoshi, relates to a spherical silica and a binder which may include organic pigments such as styrene based plastic pigments in order to improve color forming, optical density, dot shape, ink absorption and to provide coated layer strength. The incidental disclosure of the use of a plastic pigment is not the focus of the coating and it is not used for water resistance. Further, the patent does not mention the essential requirement of fusing or heating the printed image which is an essential step of the process.
U.S. Pat. No. 4,910,084, Yamasaki et al, describes the use of a poly(dialkanol allylamine) or a poly(dialkanol modified alkylene glycol) to provide water resistance and light resistance. There is no mention in the disclosure of the use of plastic pigments, latexes or the requirement to fuse them.
U.S. Pat. No. 4,944,988, Yasuda et al, relates to one coating layer which includes a resinous binder and has a pigment dispersed in the resinous binder to provide a substrate with high absorption, good print quality and surface strength. This patent does not describe a water resistant coating nor does it relate to the use of plastic pigments.
U.S. Pat. No. 5,185,213, Fujita et al, relates to high water resistance for severe environmental outdoor uses by forming a pigment coating layer of calcium carbonate or kaolin clay and a specific resin for water resistance. The binder consists of an epoxy resin and a thermoplastic resin. The thermoplastic resin is a conjugated diene copolymer latex. This patent addresses latexes and focuses on the crosslinking effect with the pigment and resin to provide water resistance. There is no mention of the necessity to fuse or heat the latex.
U.S. Pat. No. 5,281,467, Shimada et al, addresses calcium carbonate-compounded silica and other pigments as well as cationic polyelectrolytes which are coated by a cast coating method to produce a material with resistance. The coating method is vastly different from that set forth in the application, and the water resistance is provided by the cationic polymers and not by plastic pigments. The plastic pigments set forth in the invention are not fused or heated.
U.S. Pat. No. 5,302,249, Malhotra et al, relates to coatings which include a desizing component and a hydrophilic polymer to provide a rapid drying paper without print-through and intercolor bleed. Plastic pigments are not suggested or used in this patent.
U.S. Pat. No. 5,405,678, Bilodeau, relates to a hydrophobic polymeric latex which is not fully coalesced and provides a porous coating. The patent does not mention water resistance nor does it discuss the concept of heat fusing or melting. The latex particles remain as discrete spheres on the paper substrate.
Canadian Patent No. 2,214,210 relates to special paper and a process for producing the special paper. The patent addresses applying a film-forming coating that contains organic pigments and binders to at least one side of a paper. Nowhere does the patent contemplate the use of discrete particles of a plastic pigment material and its application to a “coated” paper which acts as the ink receiving layer. The patent fails to recognize the unexpected benefit of coating the paper base, nor does it recognize the unique and beneficial use of discrete particles to obtain a durable finish for ink jet printed images.
The discrete particles facilitate the integration of ink jet ink in the voids and interstices present therewith to obtain the a desired result.
It is an objective of the process and coating to provide a water-resistant plastic pigment coating for ink jet substrates of any size.
It is a further objective of the invention to provide an end product which is durable, i.e., it is water-resistant, has some lightfastness, is scratch resistant, and is longer lasting than unprotected ink jet images.
It is a further objective of the invention to provide a coating which is fused to provide an end product which is durable and is comparable to laminated ink jet images.
SUMMARY OF THE INVENTION
The invention focuses on a method and a coating for providing water resistance to ink jet substrates. The method focuses on the use of a plastic pigment composed of discrete particles being coated onto an ink receiving layer and then being subsequently heated to a temperature at, or above, its melting point to form a fused and water-resistant durable coating layer.
The water resistance is provided by using plastic pigments which can include but are not limited to styrene polymers, acrylic polymers, or acrylic urethane polymers. The plastic pigments remain as discrete particles until the temperature goes at, or above, their melting point, at which time they flow and form a continuous, water impermeable film.
REFERENCES:
patent: 4785313 (1988-11-01), Higuma et al.
patent: 4900620 (1990-02-01), Tokita et al.
patent: 4901084 (1990-02-01), Huguenin et al.
patent: 4902568 (1990-02-01), Morohoshi
patent: 4944988 (1990-07-01), Yasuda et al.
patent: 5185213 (1993-02-01), Fujita et al.
patent: 5281467 (1994-01-01), Shimada et al.
patent: 5302249 (1994-04-01), Malhotra et al.
patent: 5405678 (1995-04-01), Bilodeau
patent: 5545504 (1996-08-01), Keoshkerian et al.
patent: 5936008 (1999-08-01), Jones et al.
patent: 6147139 (2000-11-01), Shaw-Kleine et al.
patent: 6357871 (2002-03-01), Ashida et al.
patent: 2214210 (1998-02-01), None
patent: 2214210 (1998-02-01), None
patent: 0 826 823 (1998-03-01), None
Hackh's Chemical Dictionary, 4thEdition, p. 287, 1969.
Hong Yaoliang
Koenig Mike
Mets Jeanlynn
Tomimasu Hiroshi
Yang Jerry
Doyle Michael J.
Gitler Stewart L.
International Paper Company
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