Plasmon assisted enhancement of organic optoelectronic devices

Optical: systems and elements – Optical modulator – Light wave temporal modulation

Reexamination Certificate

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C359S254000

Reexamination Certificate

active

06999222

ABSTRACT:
Optoelectronic devices and methods for their fabrication having enhanced and controllable rates of the radiative relaxation of triplet light emitters are provided exemplified by organic light emitting devices based on phosphorescent materials with enhanced emission properties. Acceleration of the radiative processes is achieved by the interaction of the light emitting species with surface plasmon resonances in the vicinity of metal surfaces. Non-radiative Förster-type processes are efficiently suppressed by introducing a transparent dielectric or molecular layer between the metal surface and the chromophore. For materials with low emission oscillator strengths (such as triplet emitters), the optimal separation distance from the metal surface is determined, thus suppressing energy transfer and achieving a significant acceleration of the emission rate.

REFERENCES:
patent: 4649280 (1987-03-01), Holland et al.
Raether, H., “Surface plasmons on smooth and rough surfaces and on gratings.”Springer tracts in modern physics, vol. 111, Springer-Verlag, Berlin, Heidelberg, New York, 1988.
Snoeks, E. et al., “Measuring and Modifying the Spontaneous Emission rate of Erbium near an Interfact.”Physical Review Letters, 74(13):2459-2462 (1995).
Vo-Dinh, T., “Surface-enhanced Raman spectroscopy using metallic nanostructures.”Trends in analytical chemistry, 17(8+9):557-582 (1998).
Weissberger, A. et al., “Physical Methods in Chemistry, Part III.”Wiley InterscienceNew York, 1972.
Weitz, D.A. et al., “The enhancement of Raman scattering, resonance Raman scattering, and fluorescence from molecules adsorbed on a rough silver surface.”The Journal of Chemical Physics, 78(9):5324-5338 (1983).
Amos, R.M. et al., “Modification of the spontaneous emission rate of Eu3+ ions close to a think metal mirror.”The American Physical Society, 55(11):7249-7254 (1997).
Brust, M. et al., “Synthesis of thio-derivatized gold nanoparticles in a 2-phase liquid-liquid system.”R.J. Chem. Soc., Chem. Commun., 801 (1994).
Chew, H., “Transition rates of atoms near spherical surfaces.”The Journal of Chemical Physics, 87(2):1355-1360 ((1987).
Förster, T., “Intermolecular energy migration and fluorescence.”Ann. Phys.2, 55 (1948).
Gersten, J. et al., “Spectroscopic properties of molecules interacting with small dielectric parties.”J. Chem. Phys. 75(3), 1139 (1981).
Gong, X. et al., “High-Efficiency Polymer-Based Electrophosphorescent Devices.”Advanced Materials, 14(8):581-585 (2002).
Gryczynski, I. et al., “Multiphoton Excitation of Fluorescence near Metallic Particles: Enhanced and Localized Excitation.”The Journal of Chemical Physics, 106:2191-2195 (2002).
He, L. et al., “Colloidal Au-Enhanced Surface Plasmon Resonance for Ultrasensitive Detection of DNA Hybridization.”The Journal of Chemical Physics, 122:9071-9077 (2000).
Lakowicz, J.R., “Radiative Decay Engineering: Biophysical and Biomedical Applications,”Analytical Biochemistry, 298:1-24 (2001).
Liz-Marzan, L.M. et al., “Synthesis of Nanosized Gold-Silica Core-Shell Particles.”Langmuir12:4329-4335 (1996).
Lue, J.T. et al., “Surface plasmon enhanced optical second harmonic generation in ultra-thin metallic films.”J. Nonlinear Opt. Phys. 4, 503 (1999).
Patel, N.K. et al., “High-Efficiency Organic Light-Emitting Diodes.”IEEE Journal on Selected Topics in Quantum Electronics, 8(2):346-361 (2002).
Philpott, M.R., “Effect of surface plasmons on transitions in molecules.”The Journal of Chemical Physics, 62(5):1812-1817 (1975).

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