Piperazine intermediates

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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540314, 540316, 544357, 544358, C07D50122, A61K 31545

Patent

active

050157361

ABSTRACT:
A new compound called N,N'-carbonyl-bis-(4-ethyl-2,3-dioxo)-piperazine of Formula I ##STR1## A process for the preparation thereof based on the reaction of 4-ethyl-2,3-dioxo-piperazine or a trimethylsilyl derivative thereof with carbonyl chloride or a derivative thereof.
The use of the compound of Formula I as an intermediate in the preparation of compounds of Formula II ##STR2## where R is a radical, substituted in alpha position, of a molecule of an acid selected from the group formed by phenylacetic acid, p-hydroxy phenylacetic acid, a 6-(phenylacetamido)-penicillanic acid and a 7-(phenylacetamido)-cephalosporanic acid.

REFERENCES:
patent: 3763091 (1973-10-01), Crescenzi et al.
patent: 4110327 (1978-08-01), Saikawa et al.
patent: 4110328 (1978-08-01), Diamond
patent: 4200744 (1989-04-01), Saikawa et al.
patent: 4436921 (1984-03-01), Hori et al.

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