Pillaring layered silicates with a mixture of swelling agent and

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Silicon containing or process of making

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502350, 502 84, 502 63, 502242, 502243, 502246, 502250, 502254, 502258, 502263, 423 70, 423333, 423 71, 423331, 423332, B01J 2106

Patent

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050682164

ABSTRACT:
There is provided a method for pillaring a layered silicate, such as kenyaite, with polymeric oxide by using a single step treatment with a mixture of swelling agent and pillar precursor. The swelling agent may be an organic cation, such as a cetyltrimethylammonium cation, and the pillar precursor may be a compound which is capable of hydrolyzing to form a polymeric oxide. Tetraethylorthosilicate is an example of such a pillar precursor.

REFERENCES:
patent: 4831006 (1989-05-01), Aufdembrink
patent: 4859648 (1989-08-01), Landis et al.

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