Pigment granulates for coloring building materials

Details Pigment granulates for coloring building materials Pigment granulates for coloring building materials

2003-12-02

2004-08-24

Koslow, C. Melissa (Department: 1755)

Compositions: coating or plastic

Materials or ingredients

Pigment, filler, or aggregate compositions, e.g., stone,...

C106S502000, C106S472000, C106S476000, C106S499000

Reexamination Certificate

active

06780234

ABSTRACT:

The invention pertains to pigment granulate for the coloring of homopolar media, like asphalt, bitumen, bituminous materials, tar, and plastics, and processes for the manufacture of such granulates.
At present, in addition to organic pigments, inorganic pigments, especially those based on different iron oxides, are also used to color homopolar materials, especially asphalt and plastics. Compared to powders and pastes, pigment granulates exhibit very considerable advantages in this regard, for example in their handling, their prevention of dust and the like, but also in regard to their dispersing properties.
The use of aqueous carbon preparations (containing 30 to 80% water) as pearl granulates for coloring in the cement industry is known from DE-A1 29 08 202. This process cannot be applied to other pigments, and granulates with such water contents are fundamentally disadvantageous, also for applications involving asphalt and plastics.
The granulation of pigments together with binders through spray granulation is known from DE-A1 29 40 156. Pigment granulates produced in this way are used to manufacture inks, to color plastics, lacquers, and the like. There is no connection to the coloring of building materials, asphalt, and the like.
Color granulates for building materials containing more than 5 to 50% by weight of water are known from EP-A2 0 191 278.
EP-A1 0 567 882 describes pelletized, compacted, and sprayed granulates containing binders, such as especially machine oil, wax, paraffin, and the like, which are to be used to color asphalt, among other things. In addition to the binders, substances like lignin sulfonate, molasses, starch, and the like can be used. According to this disclosure, substances like lignin sulfonate alone cannot be used as binders.
In the context of this description, “granulates” means every material whose mean grain size in comparison to the original material is increased by a treatment stage. Therefore, “granulates” means not only spray granulates and compacting granulates but, for example, also products of a moist treatment with subsequent pulverizing.
On account of their considerable advantages, in comparison to powders, pastes, and the like, granulates have been used for decades on a large scale industrially. Granulation has been accepted for a long time for the processing of pigments as well.
Experience acquired with pigment granulates in other areas cannot simply be transferred to the coloring of building materials, asphalt, and the like. In practice, granulates, which theoretically should be almost perfectly suitable, often prove inadequate because they do not combine all of the required properties.
Although often an excellent solidity of the granulate is achieved, which counteracts its destruction during packaging and transport and restricts the production of dust, on the other hand, its dispersability can be impaired, resulting in the desired homogeneous coloring and the required color intensity not being achieved.
On the other hand, granulates with excellent color intensity and easy dispersability are often too soft and already disintegrate before they are worked into the asphalt or plastic, which can result in increased dust production, in residues in the packaging, in reduced flowability and in corresponding frequent incorrect dosages.
Of the various methods of granulation, spray granulation has become generally accepted in practice, while, for example, fluidized bed granulations, which is fully comparable theoretically, has not yet produced any usable granulates.
Proposals have recently become known to forego granulates completely and, instead, to use coated powders. WO 97/20892 is given as an example. It remains to be seen whether in this way broad particle size distributions due to clumping can be avoided and whether such coated powders can be used without producing the dust problems typical of the prior art before pigment granulates were introduced.
In order to promote the dispersion and distribution of pigment granulates, wetting and binding agents are used which are chosen in such a way that the granulate disintegrates with the desired dispersing effect. For the coloring of homopolar media, such as especially asphalt and plastics, hydrophobic compounds, like oils and waxes, which guarantee an adequate dispersability of the granulates in the hydrophobic application medium, are traditionally used as binders for the mixture to be granulated. The disadvantages of mixtures to be granulated which are based on homopolar solvents are, first, the high costs in comparison to a mixture based on water, for example, and, second, the fact that special technical devices and security measures are required for the evaporating organic binders, like oils and waxes where granulates are spray dried.
Water-based wetting agent and binder mixtures, for which water-soluble wetting agents and binders, like lignin sulfonate and the like, exhibit the disadvantage, however, the pigment cannot be homogeneously distributed in a homopolar application medium, like asphalt, bitumen, or plastic. This result in an uneven coloring, which is undesirable.
Therefore, an essential objective of the invention is to propose, against this background, a process for the coloring of homopolar media, like asphalt, bitumen, bituminous materials, tar, and plastics, by means of pigment granulates which promotes the coloring by the pigments and at the same time improves the dispersion of the pigment in a homopolar application medium. Another objective of the invention is to present a process which promotes the sprayability of the granulate.
The features defined in the independent claims achieve this objective.
Advantageous developments are described in the dependent claims.
The objective of the invention is solved by the pigments, in particular iron oxides and/or soot pigments, and the traditional wetting and binding agents, also being mixed during the manufacture of the pigment granulates with at least one agent which promotes the coloring and the distribution of the pigment in a homopolar media and/or at least one dispersing agent for polar systems. Surprisingly, it was found that the agents to promote the coloring and the distribution of the pigment in a homopolar media in accordance with this invention act in such a way that a lipophilic coating is produced on the granulate as a result of which the dispersion and, therefore, the homogeneous distribution of the pigment in the homopolar media, like asphalt, bitumen, bituminous materials, tar, and plastics, is promoted and, consequently, also the coloring of the homopolar media is promoted in an above-average manner.
Such an agent which promotes the coloring and the distribution of the pigment and which can be used to manufacture the inventive pigment granulate is preferably a wax or a mixture of several waxes. When using waxes, attention must be paid to the wax having both a high scratch and abrasion resistance. In a preferred embodiment of the invention, waxes with these properties have a melting point in the 50° C. to 200° C. range, preferably 50° C. to 130° C.
It is irrelevant with this invention whether the waxes are natural or synthetic in origin. Preferably, however., synthetic waxes are used, like polyalkylene waxes, especially polyethylene waxes, polyethylene glycol waxes, paraffin waxes, styrene acrylate waxes, polytetrafluoroethylene waxes, and the like.
With this invention, non-ionogenic waxes, waxes with anionic ionogenity, waxes with cationic ionogenity and combinations of these waxes are used. Preferably, wax mixtures are used, in which case both mixtures of waxes with anionic and/or cationic ionogenity or mixtures of non-ionogenic waxes as well as mixtures of non-ionogenic waxes and waxes with anionic or cationic ionogenity can be used. Especially preferred, mixtures of polyethylene wax and styrene-acrylate wax or mixtures of polyethylene wax and paraffin wax can be used.
In order to increase the solid contents, especially of the pigment contents, in the mixture to be granulated, in accordance with the invention, di

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