Piezoelectric ceramic composition, and high power output...

Details Piezoelectric ceramic composition, and high power output... Piezoelectric ceramic composition, and high power output...

2002-03-26

2003-04-08

Koslow, C. Melissa (Department: 1755)

Compositions

Piezoelectric

Lead, zirconium, titanium or compound thereof containing

C501S136000

Reexamination Certificate

active

06544433

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the invention
The present invention relates to a piezoelectric ceramic composition for use in a piezoelectric transformer and the like. Particularly, the present invention relates to a piezoelectric ceramic composition in which the mechanical quality factor Qm, the electromechanical coupling factor Kp and the dielectric constant are superior, and to a high power output piezoelectric transformer made of the same composition.
2. Description of the prior art
The discovery of the piezoelectric ceramic was such that BaTiO
3
was discovered at the middle of 1940s, and then, Pb(Zr, Ti)O
3
(to be called simply “PZT” below) having more superior piezoelectric properties was developed thereafter. This material has been widely applied to high voltage generators, ultrasonic apparatuses, sound apparatuses, communication apparatuses, and other various sensors.
PZT is a solid solution form of PbZrO
3
and PbTiO
3
, and has a perovskite structure, while it has superior piezoelectric properties. In order to make the composition variation easier than this two-component system and to improve the piezoelectric properties, there have been developed three-component system composite perovskite compounds. Among these three-component system compounds, attention has been focused on: Pb(Mg,Nb)O
3
—Pb(Zr,Ti)O
3
, Pb(Mg,Ta)O
3
—Pb(Zr,Ti)O
3
, and Pb(Mn,Nb)C
3
—Pb(Zr,Ti)O
3
.
Recently there has been reported a piezoelectric ceramic composition in which the sintering density is improved, and the electromechanical coupling factor is raised to 0.57 by the PSN-PZT series, that is, {Pb[(Sb
1/2
Nb
1/2
)O
3
—PZT series+MnO
2
} (Hiromuohuchi; J. Appl. Phys. Vol. 34 (1995) PP 5298-5302). However, this ceramic composition is low in the dielectric constant (700) and in the mechanical quality factor (1,000), and therefore, it cannot be used in a high power output apparatuses.
The impedance of the general fluorescent lamps is as low as several hundred &OHgr; to several &OHgr; when lighted, whereas their output power is high i.e., in the order of 10-100 watts. If the piezoelectric ceramic material is to be used for a high power, first the generation of heat, the non-linearity, the degradation of the piezoelectric properties and the mechanical strength have to be solved. In order to achieve this, first the mechanical quality factor and the electromechanical coupling factor have to be high even under a high input power, so that the energy conversion efficiency can be improved to decrease the internal loss so as to decrease the thermal radiation. Second, the mechanical oscillations are high, and therefore, the grain size has to be made fine, thereby increasing the mechanical strength.
If the piezoelectric material is to be used in the transformer for a high power fluorescent lamp, then the structure of the transformer as well as the physical properties of the material is important.
FIG. 1
a
illustrates a typical example of a piezoelectric transformer
10
which is used in an inverter, in which the reference number
20
represents a power supply of an input source. This transformer is the Rosen type in which the thickness oscillations and the lengthwise oscillations are utilized.
FIG. 1
b
is a side view of the transformer
10
. In the piezoelectric transformer of
FIG. 1
b
, a pair of input electrodes
14
are respectively formed on the bottom and top of a piezoelectric block
12
, and the input electrodes
14
are polarized in the thickness direction. An output part consists of an electrode
16
which is dispose on a side of the piezoelectric block, and is polarized in the lengthwise direction. If the piezoelectric transformer is to be stepped up, then an ac voltage corresponding to the resonance frequency is supplied to the input electrodes
14
. Then the supplied electrical signals are converted to strong mechanical oscillations in the thickness direction near the input electrodes of the piezoelectric block
12
. These oscillations lead to lengthwise oscillations of the output side, and consequently, a stepped-up high voltage with a frequency same as the input frequency is outputted through the output electrode
16
. The stepping-up of the voltage becomes maximum when the frequency of the input voltage is same as the oscillation frequency of the output side. Under this condition, the ratio of the stepping-up of the piezoelectric transformer depends on the impedance of the load. That is, if a low impedance of load is connected to the output side, the ratio of th e stepping-up becomes less than several scores. The magnitude of the load impedance is different depending on the 1; ind of lamps in the case where the piezoelectric transformer is used in the cold cathode ray tube or in the fluorescent: lamp. However, if the piezoelectric transformer is manufactured at the optimum conditions, then a high stepping-up ratio can be maintained. Thus in the normal case where a high impedance is connected before the lighting, and where the load impedance is lowered after the lighting, a sufficient stepping-up ratio can be maintained, so that it can be used in the cold cathode ray tube or in the fluorescent lamp.
Recently, there has bee n known a filter
10
in which h the oscillation mode is as shown in
FIG. 2
b
.
FIG. 2
b
is a side view of the filter
10
. As shown in
FIG. 2
b
, an input electrode
14
is formed on the top of a piezoelectric block
12
, and an output electrode
16
is formed around the input electrode
14
keeping a certain distance from the latter. On the bottom of the piezoelectric block
12
, there is formed a second electrode
18
which is a common electrode. If a voltage is supplied into the input electrode
14
, then the supplied electrical signals are converted to mechanical oscillations from the center toward the peripheral portions, and then, output signals proportional to the mechanical oscillations are outputted through the out put electrode
16
. However, if this structure is used in a high power apparatus, them stress is imposed on the middle of the edge portions, with the result that the device is damaged or it s efficiency is degraded.
As described above, if the piezoelectric ceramic is to be used in a high output power apparatus, then the problems of the dielectric constant, the mechanical quality factor Qm and the electromechanical coupling factor Kp have to be solved first, and a proper structure of the transformer has to be provided also.
SUMMARY OF THE INVENTION
The present invention is intended to solve the above described problems of the conventional techniques.
Therefore it is an object of the present invention to provide a piezoelectric ceramic composition in which the dielectric constant is 1,320 or more, the electromechanical coupling factor is 0.520 or more, and a mechanical quality factor is 1440 or more, and a high output power piezoelectric transformer 6obtained by using the piezoelectric ceramic composition.
It is another object of the present invention to provide a high output power piezoelectric transformer, in which the piezoelectric ceramic composition is used to construct the transformer so that the high output power characteristics are satisfied, and the operation is stable, by designing particular electrodes.
In achieving the above objects, the piezoelectric ceramic composition according to the present invention includes: Pb[(Sb
1/2
Nb
1/2
)
x
(Zr
0.495
Ti
0.505
)
1−x
]O
3
+yPbO+zMnO, where x is 0.01-0.05, y is 0.3-0.6 wt %, and z is 0.7 wt % or less.
In another aspect of the present invention, the high output power piezoelectric transformer according to the present invention obtained by using a piezoelectric ceramic composition satisfying Pb[(Sb
1/2
Nb
1/2
)
x
(Zr
0.495
Ti
0.505
)
1−x
]O
3
+yPbO+zMnO, where x is 0.01-0.05, y is 0.3-0.6 wt %, and z is 0.7 wt % or less.
In still another aspect of the present invention, the high output power piezoelectric transformer according to the present invention includes: a piezoelectric block composed of Pb[(Sb
1/2
Nb

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