Phthalocyanine complex-filled fluids

Compositions – Electrolytes for electrical devices

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252 497, 252 52R, 252 54, 252 56R, C10M11930

Patent

active

049752103

ABSTRACT:
A lubricating composition of about 90 to about 99% by weight of a lubricant and about 1 to about 5% by weight of an organometallic phthalocynaine, preferably a polymeric organometallic phthalocyanine complex, including nitrogen-substituted analogues thereof, where the complexed metal ion is preferably a Group IVA metal and provides increased time of machine operation to failure by improving oil lubricated bearing performance. Phthalocynanine peripheral ring substituents and attached to the phthalocyanine increase solubility in aqueous and organic lubricants.

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patent: 4769163 (1988-09-01), Boes et al.
"Electrically-Conductive Group IV A Phthalocyanine Polymers," by Karl Frederick Schoch, Jr., Northwestern University (Jun., 1982).
"Cofacial Assembly of Partially Oxidized Metallomacrocyclics as an Approach to Controlling Lattice Architecture in Low-Dimensional Molecular Solids, Chemical and Architectural Properties of the `Face-to-Face` Polymers ([M(Phthalocyanato)0].sub.n) where M=Si,Ge,Sn," by C. W. Dirk et al., J. Am. Chem. Soc., 105, 1539 (1983).
"The Phthalocyanines, vol. II Manufacture and Applications," by F. H. Moser et al., pp. 53 to 89, CRC Press, Inc. (1983).
"Graphite Lubricant Combinations for High-Temperature Applications," by L. C. Lipp, Lubrication Engineering, vol. 22, No. 25, May (1966), pp. 187-195.
"Friction Properties of Phthalocyanine Pigments," by G. Salomon, Wear, vol. 10, No. 5, pp. 383 to 396 (1967).

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