Photothermographic composition and process

Radiation imagery chemistry: process – composition – or product th – Radiation sensitive product – Silver compound sensitizer containing

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430353, 430620, G03C 102

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active

042647258

ABSTRACT:
In a photothermographic silver halide composition capable of being coated on a support comprising a hydrophilic photosensitive silver halide emulsion containing a gelatino peptizer with an organic solvent mixture, a hydrophobic binder and an oxidation-reduction image-forming composition comprising (i) a silver salt of a long-chain fatty acid with (ii) an organic reducing agent, improvements are provided by a solvent mixture comprising a combination of (A) an alcohol photographic speed-increasing solvent which is a compound selected from the group consisting of benzyl alcohol photographic speed-increasing solvents and 2-phenoxyethanol speed-increasing solvents with (B) an aromatic hydrocarbon solvent that is compatible with the alcohol solvent and (C) 0 to 10% by weight of the solvent mixture of such hydrophobic binder. The described photothermographic composition can be prepared by very thoroughly mixing, such as ultrasonic wave mixing, (I) a hydrophilic photosensitive silver halide emulsion with (II) an organic solvent mixture comprising described (A), (B) and (C), and then very thoroughly mixing the resulting product with (III) comprising (a) a hydrophobic binder and (b) an oxidation-reduction image-forming composition comprising (i) a silver salt of a long-chain fatty acid with (ii) an organic reducing agent, typically in an organic solvent. The photothermographic composition can be coated on a suitable support to provide a photothermographic element.

REFERENCES:
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patent: 3480436 (1969-11-01), Wilson
patent: 3666477 (1972-05-01), Goffe
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patent: 3844797 (1974-10-01), Willems et al.
patent: 3909271 (1975-09-01), Ikenoue et al.
patent: 4080211 (1978-03-01), Van Paesschen et al.
Product Licensing Index, vol. 92, Publ. 9232, Dec. 1971.
Research Disclosure, vol. 117, Item No. 11723, Jan. 1974.
Research Disclosure, vol. 170, Item No. 17029, Jun. 1978.

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